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Sergey Mikhalev (Nationality Portuguese) completed his doctorate degree in the Technology of Rare, Radioactive and Trace Elements on 2004/01/19 from the Ural State Technical University - UPI. Between 2004-2007, Sergey Mikhalev was the Assistant Professor in the Department of Rare Metals and Nanomaterials at the Ural State University, USTU-UPI, Russia, and served as the Deputy Dean of the Physical-Engineering Faculty. During this time, he gained extensive supervision experience, being actively involved in the teaching and mentoring of large numbers of graduate and postgraduate students (supervised more than 20 graduate works). He has published 52 articles in International SCI journals in the field of solid-state electrochemistry and 13 conference publications related to the electrochemistry of melts. Sergey Mikhalev has participated as a Post-Doctoral Fellow in 7 projects and served as the Principal Investigator of the exploratory project Molten Alloy Electrochemical Cells for Plastic Waste Conversion (EXPL / EMS-ENE / 1497/2013). His expertise lies in Materials Engineering with a strong focus on Electrochemistry, especially on electrochemical measurements performed in challenging environments such as melts. His key areas of specialization include molten salts, molten metals, solid-state electrochemistry, proton conductors, oxide ion conductors, coulometric titration, electrodeposition of metals, corrosion protection, metallurgy, electrorefining, and electrodeposition. Sergey Mikhalev has collaborated with 51 co-authors on scientific publications. He has extensive experience in the research and development of both high-temperature batteries and solid-state batteries, including their design, electrochemical performance optimization, and materials innovation for energy storage systems. His work has included advanced studies on the use of molten salts and solid electrolytes for high-temperature energy storage applications, as well as the development of solid-state battery technologies using proton and oxide-ion conductors. Sergey Mikhalev is the leading author of 3 patents related to the use of sulfates in energy storage: International Patent number: WO/2018/154488 (Publication date: 30.08.2018) US Patent number: US/2019/0379009 (Publication date: 12.12.2019) European Patent number: EP3586385 (Publication date: 01.01.2020).
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Identification

Personal identification

Full name
Sergey Mikhalev

Citation names

  • Mikhalev, Sergey

Author identifiers

Ciência ID
0017-D46D-A069
ORCID iD
0000-0001-5452-8191

Knowledge fields

  • Exact Sciences - Chemical Sciences - Electrochemistry
  • Exact Sciences - Chemical Sciences - Electrochemistry
  • Exact Sciences - Chemical Sciences - Electrochemistry
  • Engineering and Technology - Electrotechnical Engineering, Electronics and Informatics - Automation and Control Systems

Languages

Language Speaking Reading Writing Listening Peer-review
English Advanced (C1) Advanced (C1) Advanced (C1) Advanced (C1)
Russian Advanced (C1) Advanced (C1) Advanced (C1) Advanced (C1)
Portuguese Intermediate (B1) Intermediate (B1) Intermediate (B1) Intermediate (B1)
Education
Degree Classification
2000/10/01 - 2004/01/19
Concluded
 Technology of rare, radioactive and trace elements (Doutoramento)
Ural State Technical University - UPI, Russia
"Electrolytic deposition and refining of hafnium metal in chloride melts" (THESIS/DISSERTATION)
 PhD
1994/09/01 - 2000/04/01
Concluded
 Engineer in Chemical Technology of Materials of Modern Energetics (Licenciatura)
Ural State Technical University - UPI, Russia
"Kinetics of electrode reactions in beryllium containing chloride and chloride-fluoride melts" (THESIS/DISSERTATION)
 Engineer
Affiliation

Science

Category
Host institution 		Employer
2019/01/31 - Current Contracted Researcher (Research) Universidade de Aveiro, Portugal
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2010 - 2019/01/30 Postdoc (Research) Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2008/05/10 - 2010 Postdoc (Research) Universidade de Aveiro CICECO, Portugal
2005/03 - 2005/10 Postdoc (Research) Universidade de Aveiro CICECO, Portugal

Teaching in Higher Education

Category
Host institution 		Employer
2004 - 2007 Lecturer (University Teacher) Ural State Technical University - UPI, Russia
2003 - 2004 Lecturer (University Teacher) Ural State Technical University - UPI, Russia

Others

Category
Host institution 		Employer
2007/10 - 2008/03 Engineer Group of companies “Pack-Servis” , Russia
1998 - 2000 Engineer Ural State Technical University - UPI, Russia
Projects

Grant

Designation Funders
2021/01 - 2025/12 Laboratório Associado de Sistemas Inteligentes
168241UID
LA/P/0104/2020
10.54499/LA/P/0104/2020
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal

Universidade Nova de Lisboa Centro de Tecnologias e Sistemas, Portugal

Instituto Politécnico do Porto Centro de Investigação em Sistemas Computacionais Embebidos e de Tempo-Real, Portugal

Universidade do Minho, Portugal

Universidade do Porto Faculdade de Ciências, Portugal

Universidade do Porto Centro de Matemática, Portugal

Universidade Nova de Lisboa, Portugal

Universidade do Porto Laboratório de Inteligência Artificial e Ciência de Computadores, Portugal

Universidade de Aveiro, Portugal

Universidade do Minho Instituto de Polímeros e Compósitos, Portugal

Universidade de Aveiro Instituto de Engenharia Eletrónica e Informática de Aveiro, Portugal

Universidade do Minho Centro ALGORITMI, Portugal

Universidade Nova de Lisboa Unidade de Investigação e Desenvolvimento em Engenharia Mecânica e Industrial, Portugal

Universidade de Coimbra, Portugal

Universidade de Coimbra Departamento de Engenharia Civil, Portugal

Instituto Politécnico do Porto Instituto Superior de Engenharia do Porto, Portugal

Instituto Politécnico do Porto Grupo de Investigação em Engenharia e Computação Inteligente para a Inovação e o Desenvolvimento, Portugal

Instituto Politécnico do Cávado e do Ave, Portugal

Universidade do Porto Faculdade de Engenharia, Portugal
Fundação para a Ciência e a Tecnologia
Ongoing

Contract

Designation Funders
2019/01/01 - 2019/12/31 Centro de Tecnologia Mecânica e Automação
UID/EMS/00481/2019
Universidade de Aveiro, Portugal
 Fundação para a Ciência e a Tecnologia
Concluded
2017 - 2019 Combustíveis sintéticos de elevado rendimento a partir do biogás.
PTDC/CTM-ENE/6319/201
Post-doc Fellow
2016 - 2017 Phase transformations, microstructural, compositional and texture effects in nano-structured perovskite-related oxide materials for oxygen storage, catalytic and electrode applications.
IF/00280/2012
Post-doc Fellow
2012/05/02 - 2015/09/30 ORIEL - Filmes Finos de Silicato de Lantânio com Orientação Preferencial para Electrólitos de IT-SOFCs
PTDC/CTM-CER/118933/2010
Universidade de Aveiro CICECO, Portugal

Universidade de Aveiro, Portugal

Universidade de Coimbra, Portugal

Universidade de Coimbra Centro de Engenharia Mecânica Materiais e Processos, Portugal
Fundação para a Ciência e a Tecnologia
Concluded
2014/03/01 - 2015/07/31 Molten alloy electrochemical cells for plastic waste conversion.
EXPL/EMS-ENE/1497/2013
Principal investigator
2013 - 2014 Nowel Layered Ferrite Materials with Mixed Ionic-Electronic Conductivityfor Application in Alternative Energy Sources.
PTDC/CTM/64357/2006 (FCT)
 N/A
2011/01/01 - 2013/12/31 Desenvolvimento e validação de novos métodos de análise de mecanismos de transporte iónico em redes cristalinas complexas de óxidos e de previsão de parâmetros determinantes do desempenho destes materiais
PTDC/CTM-CER/114561/2009
Universidade de Aveiro, Portugal

Universidade de Lisboa Instituto Superior Técnico, Portugal

Universidade de Aveiro CICECO, Portugal
Fundação para a Ciência e a Tecnologia
Concluded
2012 - 2013 Production of pure hydrogen by reforming of biogas and electrochemical separation (HYDEL)
PTDC/CTM/100412/2008, 2010-2013
Post-doc Fellow
2011 - 2012 Extension of Electrochemically Active Sites in SOFC anodes-(E-a-s-i Anode)
PTDC/CTM/105424/2008, 2010-2013
Post-doc Fellow
2010 - 2011 Nowel Layered Ferrite Materials with Mixed Ionic-Electronic Conductivityfor Application in Alternative Energy Sources.
PTDC/CTM/64357/2006 (FCT)
Post-doc Fellow
2008 - 2009 ULCOS -Ultra Low CO2 Steelmaking
NMP2/CT/2004/515960
Post-doc Fellow
2005/03 - 2005/11 ULCOS -Ultra Low CO2 Steelmaking
NMP2/CT/2004/515960
Post-doc Fellow
Universidade de Aveiro, Portugal

Other

Designation Funders
2024/01/01 - 2025/12/31 ILLIANCE energy efficiency
10.54499/LA/P/0104/2020
Ongoing
Outputs

Publications

Book chapter
  1. Laura I.V. Holz; Vanessa C.D. Graça; Sergey M. Mikhalev; Francisco José Almeida Loureiro; Duncan P. Fagg. "Advanced materials for improving the (electro)catalytic processes in ammonia ceramic fuel cells". 2024.
    10.1016/b978-0-443-13547-7.00007-0
  2. Graça, V.C.D.; Loureiro, F.J.A.; Holz, L.I.V.; Mikhalev, S.M.; Araújo, A.J.M.; Fagg, D.P.. "Electrochemical ammonia synthesis: Mechanism, recent developments, and challenges in catalyst design". 497-514. 2022.
Conference abstract
  1. Mikhalev, Sergey; Graça, Vanea; Francisco J.A. Loureiro; Holz, Laura; Fagg, Duncan. "Enhaced CO2 stability of nickel doped BaCe0.9Y0.1O3- d (BCY10)". Paper presented in 5th International symposium on Materials for energy storage and conversion, (mESC-IS 2021), Akyaka, 2021.
    Published
  2. Mikhalev, Sergey; Paulo S.B. Julião; Loureiro, Francisco J. A.; Fagg, Duncan P.; Shaula, Aliaksandr L.. Corresponding author: Mikhalev, Sergey. "Antimony-lead melts for high temperature electrochemical applications". Paper presented in 4th International Conference on Nanomaterials Science and Mechanical Engineering, Aveiro, 2021.
    Published • 10.48528/mgdm-qc95
  3. Mikhalev, Sergey; Kovalevsky, Andrei; Arias-Serrano, Blanca I.; Constantinescu, Gabriel; Zakharchuk, Kiryl; Sergiienko, Sergii A.; Sh. Rasekh; et al. Corresponding author: Kovalevsky, Andrei. "Specific microstructural effects on the performance of thermoelectric oxides.". Paper presented in 4th International Conference on Nanomaterials Science and Mechanical Engineering, Aveiro, 2021.
    Published • 10.48528/mgdm-qc95
  4. Mikhalev, Sergey; Loureiro, Francisco J. A.; D. Pukazhselvan; Bdikin, Igor; Shaula, Aliaksandr L.; Fagg, Duncan P.. Corresponding author: Loureiro, Francisco J. A.. "Magnesium hydride-added titania anode for Li-ion battery.". Paper presented in 4th International Conference on Nanomaterials Science and Mechanical Engineering, Aveiro, 2021.
    Published • 10.48528/mgdm-qc95
  5. Mikhalev, Sergey; Graça, Vanessa C. D.; Holz, Laura; Francisco J.A. Loureiro; Duncan P. Fagg. Corresponding author: Graça, Vanessa C. D.. "The influence of ammonolysis temperature and time on synthesis of cubic niobium (oxy)nitride.". Paper presented in 4th International Conference on Nanomaterials Science and Mechanical Engineering, Aveiro, 2021.
    Published • 10.48528/mgdm-qc95
  6. Mikhalev, Sergey; Kovalevsky, Andrei; Zakharchuk, Kiryl; Ferreira, Nuno; Xie, Wenjie; Patrício, Sonia G.; Arias-Serrano, Blanca I.; et al. "Strontium titanate and zinc-oxide-based materials for high-temperature thermoelectric harvesting". Paper presented in 3rd International Conference on Nanomaterials Science and Mechanical Engineering (ICNMSME2020), Aveiro, 2020.
    Published
  7. Mikhalev, Sergey; Constantinescu, Gabriel; Shahed Rasekh; Kovalevsky, Andrei. "Electrical performance tuning in thermoelectric Ca3Co4O9 materials by transition metals additions". Paper presented in 3rd International Conference on Nanomaterials Science and Mechanical Engineering (ICNMSME2020), Aveiro, 2020.
    Published
  8. Mikhalev, Sergey; Holz, Laura I. V.; Francisco J.A. Loureiro; Graça, Vanessa C. D.; Diogo Mendes; Mendes, Adélio; Fagg, Duncan. "The influence of ammonolysis temperature on physical properties of vanadium oxynitride (VOxN1-x) solid solutions". Paper presented in 3rd International Conference on Nanomaterials Science and Mechanical Engineering (ICNMSME2020), Aveiro, 2020.
    Published
  9. Mikhalev, Sergey; Francisco J.A. Loureiro; Pérez-Coll, Domingo; Graça, Vanessa C. D.; Ribeiro, Alejandro F. G.; Mendes, Adélio; Duncan P. Fagg. "Proton conductivity in BCY10 in nominally dry conditions". Paper presented in 2rd International Conference on Nanomaterials Science and Mechanical Engineering (ICNMSME2019), Aveiro, 2019.
    Published
Conference paper
  1. S.M. Mikhalev*, Paulo S.B. Julião, F.J.A. Loureiro, A.L. Shaula, D.P. Fagg. Corresponding author: S.M. Mikhalev*, Paulo S.B. Julião, F.J.A. Loureiro, A.L. Shaula, D.P. Fagg. "Antimony-lead melts for high temperature electrochemical applications". Paper presented in 4th International Conference on Nanomaterials Science and Mechanical Engineering, (ICNMSME-2021)., 2021.
  2. Mikhalev, Sergey; V.V. Lobanov; I.F. Nichkov; O.I. Rebrin. "Electrolytic methods of production of copper-beryllium alloys". Paper presented in First Sci. Pract. Conf. on New Technologies and Ways of Cost Saving in Mining, Metallurgical and Heavy Machinery Industry, Verkhnyaya Pyshma, 2003.
  3. Mikhalev, Sergey; V.A. Nauman; O.I. Rebrin; L.F. Yamschikov. "Study of processes of hafnium production in chloride melts". Paper presented in II Int. Conf. Met. Non-ferrous and Rare Metals, Krasnoyarsk, 2003.
  4. O.I. Rebrin; R.Yu. Scherbakov; I.B. Polovov; S.M. Mikhalev; A.S. Muhamadeev; B.D. Vasin; V.A. Volkovich. "Investigation of kinetics of electrode processes in halide melts, containing beryllium, vanadium, niobium and hafnium". Paper presented in Molten Salts XIII, Proc. Thirteenth Int. Symp. Molten Salts, The Electrochem. Soc., Pennington, 2002.
  5. Mikhalev, Sergey; V.A. Nauman; O.I. Rebrin; R.Yu. Scherbakov; L.F. Yamschikov. "On possibility of alloying of hafnium with alkali metals during electrolysis of chloride melts". Paper presented in XIV Int. Conf. Chem. Thermodynamics, Sankt-Peterburg, 2002.
  6. Mikhalev, Sergey; L.F. Yamschikov. "Automation of temperature control on electrochemical complex". Paper presented in III Conf. Young Scientists of USTU-UPI, Ekaterinburg, 2002.
  7. Mikhalev, Sergey; A.S. Mukhamadeev; O.I. Rebrin; R.Yu. Scherbakov. "Methods of processing of chronopotentiograms". Paper presented in XII Russ. Conf. Phys. Chem. Electrochem. Molten and Solid Electrolytes, vol. 1, Nal'chik, 2001.
  8. Mikhalev, Sergey; O.I. Rebrin; R.Yu. Scherbakov. "Study of polarization of hafnium electrode in (NaCl-KCl)-HfCl4 and KCl-HfCl4 melts". Paper presented in Physico-chemical Basis of Technology of Materials of Modern Technology, Sci. Transactions of USTU-UPI, iss. 1, Ekaterinburg, 2001.
  9. Mikhalev, Sergey; L.A. Plotnikov. "Limiting current densities of deposition of hafnium metal form KCl-HfCl4 and (NaCl-KCl)-HfCl4 electrolytes". Paper presented in XI Conference on Problems of Theoretical and Practical Chemistry, Ekaterinburg, 2001.
  10. Mikhalev, Sergey; L.F. Yamschikov. "Apparatus for studying of processes of electrochemical deposition of refractory metals". Paper presented in I Conf. Young Scientists of USTU-UPI, Ekaterinburg, 2001.
  11. O.I. Rebrin; I.F. Nichkov; R.Yu. Scherbakov; S.M. Mikhalev. "Kinetics of anodic oxidation of beryllium in halide melts". Paper presented in X Kola Seminar on Electrochemistry of Rare Metals,, Apatity, 2000.
  12. O.I. Rebrin; I.F. Nichkov; R.Yu. Scherbakov; S.M. Mikhalev. "Kinetics of cathodic reduction of beryllium ions in halide melts". Paper presented in X Kola Seminar on Electrochemistry of Rare Metals, Apatity, 2000.
  13. Mikhalev, Sergey; A.S. Mukhamadeev; R.Yu. Scherbakov. "Features of polarization curves durind cathodic deposition of metals onto solid electrode". Paper presented in X Conference on Problems of Theoretical and Practical Chemistry, Ekaterinburg, 2000.
Journal article
  1. Diogo Lopes; Andrei V. Kovalevsky; Aleksey A. Yaremchenko; Sergey M. Mikhalev; F.M. Costa; Nuno M. Ferreira. "Exploring the potential of laser processing for designing TiO2-based thermoelectric materials". Journal of the European Ceramic Society (2025): http://dx.doi.org/10.1016/j.jeurceramsoc.2024.116883.
    10.1016/j.jeurceramsoc.2024.116883
  2. Bruno Miguel Gonçalves Melo; Francisco Loureiro; Sergey M. Mikhalev; d.p.fagg; L.C. Costa; M.P.F. Graça. "Alternative processing routes on CsH2PO4 proton conductors: Cold sintering and ball-milling routes". International Journal of Hydrogen Energy (2024): http://dx.doi.org/10.1016/j.ijhydene.2024.06.077.
    10.1016/j.ijhydene.2024.06.077
  3. Morena B. Farias; Allan J. M. Araújo; Laura Holz; Sergey M. Mikhalev; Carlos A. Paskocimas; d.p.fagg; Francisco Loureiro. "Sr2Fe1·5Mo0·5O6--based cathodes for solid oxide fuel cells: Microstructural considerations and composite formation with Pr-doped ceria". International Journal of Hydrogen Energy (2024): http://dx.doi.org/10.1016/j.ijhydene.2024.02.363.
    10.1016/j.ijhydene.2024.02.363
  4. D Pukazhselvan; Ihsan Çaha; Catarina de Lemos; Sergey M. Mikhalev; Francis Leonard Deepak; Duncan Paul Fagg. "Understanding the catalysis of chromium trioxide added magnesium hydride for hydrogen storage and Li ion battery applications". Journal of Magnesium and Alloys (2024): http://dx.doi.org/10.1016/j.jma.2024.03.007.
    10.1016/j.jma.2024.03.007
  5. Holz, L.I.V.; Loureiro, F.J.A.; Graça, V.C.D.; Mikhalev, S.M.; Fernandes, C.; Mendes, A.; Fagg, D.P.. "Strontium iron molybdenum oxide as electrocatalyst for nitrous oxide reduction in solid oxide fuel cells". International Journal of Hydrogen Energy 54 (2024): 25-36. http://www.scopus.com/inward/record.url?eid=2-s2.0-85161547473&partnerID=MN8TOARS.
    10.1016/j.ijhydene.2023.05.251
  6. Graça, V.C.D.; Holz, L.I.V.; Loureiro, F.J.A.; Mikhalev, S.M.; Fagg, D.P.. "Ba2NiMoO6-d as a potential electrode for protonic ceramic electrochemical cells". International Journal of Hydrogen Energy 54 (2024): 305-315. http://www.scopus.com/inward/record.url?eid=2-s2.0-85152650455&partnerID=MN8TOARS.
    10.1016/j.ijhydene.2023.03.354
  7. D. Pukazhselvan; Çaha, Ihsan; Mikhalev, Sergey; Deepak, Francis Leonard; Duncan Paul Fagg. Corresponding author: D. Pukazhselvan. "A highly active additive for magnesium hydride from the MgO-TiO2 mixed oxide family: magnesium dititanate". International Journal of Hydrogen Energy (2023):
    Accepted
  8. D, P.; Çaha, I.; Loureiro, F.J.A.; Shaula, A.L.; Mikhalev, S.M.; Deepak, F.L.; Fagg, D.P.. "Superior catalytic effect of titania - porous carbon composite for the storage of hydrogen in MgH2 and lithium in a Li ion battery". International Journal of Hydrogen Energy 48 62 (2023): 23917-23929. http://www.scopus.com/inward/record.url?eid=2-s2.0-85151322948&partnerID=MN8TOARS.
    10.1016/j.ijhydene.2023.03.226
  9. Shakel, Z.; Loureiro, F.J.A.; Melo, B.M.G.; Pukazhselvan, D.; Mikhalev, S.M.; Shaula, A.L.; Fagg, D.P.. "Investigating the grain boundary features of lithium titanium phosphate as an electrolyte for all-solid-state lithium-ion batteries and their optimization by boron doping". Journal of Energy Storage 65 (2023): http://www.scopus.com/inward/record.url?eid=2-s2.0-85152360960&partnerID=MN8TOARS.
    10.1016/j.est.2023.107387
  10. Salak, A.N.; Cardoso, J.P.; Khalyavin, D.D.; Barbier, A.; Fertey, P.; Mikhalev, S.M.; Olekhnovich, N.M.; et al. "Composition-, temperature- and pressure-induced transitions between high-pressure stabilized perovskite phases of the (1-x)BiFe0.5Sc0.5O3 - xLaFe0.5Sc0.5O3 series". Journal of Solid State Chemistry 322 (2023): http://www.scopus.com/inward/record.url?eid=2-s2.0-85149182324&partnerID=MN8TOARS.
    10.1016/j.jssc.2023.123937
  11. Pukazhselvan, D.; Çaha, I.; Mikhalev, S.; Deepak, F.L.; Fagg, D.P.. "A highly active additive for magnesium hydride from the MgO–TiO2 mixed oxide family: Magnesium dititanate". International Journal of Hydrogen Energy 48 96 (2023): 37510-37521. http://www.scopus.com/inward/record.url?eid=2-s2.0-85167815515&partnerID=MN8TOARS.
    10.1016/j.ijhydene.2022.12.363
  12. Pukazhselvan, D.; Granadeiro, C.M.; Loureiro, F.J.A.; Shaula, A.L.; Mikhalev, S.M.; Gonçalves, G.; Fagg, D.P.. "Comparative analyses of MIL-88B(Fe) and MIL-100(Fe) metal organic frameworks as active anode materials for Li ion batteries". Electrochimica Acta 465 (2023): http://www.scopus.com/inward/record.url?eid=2-s2.0-85172089266&partnerID=MN8TOARS.
    10.1016/j.electacta.2023.142989
  13. "Ionic Liquid–Poly(lactic acid) Blends as Green Polymer Electrolyte Membranes". The Journal of Physical Chemistry C 126 1 (2022): 551-562. http://dx.doi.org/10.1021/acs.jpcc.1c07536.
    10.1021/acs.jpcc.1c07536
  14. Shakel, Z.; Loureiro, F.J.A.; Antunes, I.; Mikhalev, S.M.; Fagg, D.P.. "Tailoring the properties of dense yttrium-doped barium zirconate ceramics with nickel oxide additives by manipulation of the sintering profile". International Journal of Energy Research 46 15 (2022): 21989-22000. http://www.scopus.com/inward/record.url?eid=2-s2.0-85134047154&partnerID=MN8TOARS.
    10.1002/er.8389
  15. Graça, V.C.D.; Loureiro, F.J.A.; Holz, L.I.V.; Mikhalev, S.M.; Fagg, D.P.. "Assessment of the electrical properties and chemical stabilities of BaCe0.9Y0.1O3-d and BaCe0.7Zr0.1Y0.2O3-d proton ceramic electrolytes at low temperatures, 300 to 600°C". International Journal of Energy Research 46 15 (2022): 22113-22123. http://www.scopus.com/inward/record.url?eid=2-s2.0-85137992509&partnerID=MN8TOARS.
    10.1002/er.8746
  16. Holz, L.I.V.; Graça, V.C.D.; Loureiro, F.J.A.; Mikhalev, S.M.; Mendes, D.; Mendes, A.; Fagg, D.P.. "Tailoring the anion stoichiometry and oxidation kinetics of vanadium (oxy)nitride by the control of ammonolysis conditions". Journal of Materials Chemistry C 10 14 (2022): 5608-5620. http://www.scopus.com/inward/record.url?eid=2-s2.0-85128143606&partnerID=MN8TOARS.
    10.1039/d2tc00545j
  17. Holz, L.I.V.; Loureiro, F.J.A.; Graça, V.C.D.; Mikhalev, S.M.; Mendes, D.; Mendes, A.; Fagg, D.P.. "Vanadium (oxy)nitride as a new category of anode for direct ammonia solid oxide fuel cells cells". Renewable Energy 201 (2022): 124-130. http://www.scopus.com/inward/record.url?eid=2-s2.0-85140920015&partnerID=MN8TOARS.
    10.1016/j.renene.2022.10.098
  18. Constantinescu, G.; Galatanu, A.; Tobaldi, D.; Mikhalev, S.; Suarez, D.; Paulino, T.; Zakharchuk, K.; et al. "Enhancement of Thermoelectric Performance of Donor-Doped ZnO Ceramics by Involving an In Situ Aluminothermic Reaction during Processing". Crystals 12 11 (2022): http://www.scopus.com/inward/record.url?eid=2-s2.0-85141824142&partnerID=MN8TOARS.
    10.3390/cryst12111562
  19. Pukazhselvan, D.; Shaula, A.L.; Mikhalev, S.M.; Bdikin, I.; Fagg, D.P.. "Elucidating Evidence for the In Situ Reduction of Graphene Oxide by Magnesium Hydride and the Consequence of Reduction on Hydrogen Storage". Catalysts 12 7 (2022): http://www.scopus.com/inward/record.url?eid=2-s2.0-85133139199&partnerID=MN8TOARS.
    10.3390/catal12070735
  20. Pukazhselvan, D.; Loureiro, F.J.A.; Shaula, A.; Mikhalev, S.; Bdikin, I.; Fagg, D.P.. "Anatase titania as magnesium host in Mg ion rechargeable battery with magnesium perchlorate/ethylmagnesium bromide electrolytes". Journal of Materials Science 57 18 (2022): 8442-8454. http://www.scopus.com/inward/record.url?eid=2-s2.0-85122229036&partnerID=MN8TOARS.
    10.1007/s10853-021-06793-2
  21. Graça, V.C.D.; Loureiro, F.J.A.; Holz, L.I.V.; Mikhalev, S.M.; Fagg, D.P.. "Toward improved chemical stability of yttrium-doped barium cerate by the introduction of nickel oxide". Journal of the American Ceramic Society 105 10 (2022): 6271-6283. http://www.scopus.com/inward/record.url?eid=2-s2.0-85132195315&partnerID=MN8TOARS.
    10.1111/jace.18600
  22. "Antimony-lead melts for high temperature electrochemical applications". Nanomaterials Science & Engineering (2021): Vol 3 No 2 (2021): N-Vol 3 No 2 (2021): N. https://proa.ua.pt/index.php/nmse/article/view/25983.
    10.34624/NMSE.V3I2.25983
  23. Mikhalev, Sergey M.; Julião, Paulo S.B.; Loureiro, Francisco J.A.; Kovalevsky, Andrei V.; Shaula, Aliaksandr L.; Frade, Jorge R.; Fagg, Duncan P.. "Electrochemical saturation of antimony-lead melts with oxygen: Cell design and measurement". Electrochimica Acta 395 (2021): 139206. http://dx.doi.org/10.1016/j.electacta.2021.139206.
    10.1016/j.electacta.2021.139206
  24. Loureiro, Francisco J.A.; Pukazhselvan, D.; Bdikin, Igor; Shaula, Aliaksandr L.; Mikhalev, Sergey M.; Fagg, Duncan P.. "Electrochemical behaviour of magnesium hydride-added titania anode for Li-ion battery". Electrochimica Acta 394 (2021): 139142. http://dx.doi.org/10.1016/j.electacta.2021.139142.
    10.1016/j.electacta.2021.139142
  25. Loureiro, Francisco J. A.; Ramasamy, Devaraj; Graça, Vanessa C. D.; Holz, Laura I. V.; Mikhalev, Sergey M.; Fagg, Duncan P.. "Analysis of La4Ni3O10±d-BaCe0.9Y0.1O3-d Composite Cathodes for Proton Ceramic Fuel Cells". Applied Sciences 11 8 (2021): 3407. http://dx.doi.org/10.3390/app11083407.
    10.3390/app11083407
  26. Constantinescu, Gabriel; Mikhalev, Sergey M.; Lisenkov, Aleksey D.; Lopes, Daniela V.; Sarabando, Artur R.; Ferro, Marta C.; Silva, Tiago F. da; Sergiienko, Sergii A.; Kovalevsky, Andrei V.. "Prospects for Electrical Performance Tuning in Ca3Co4O9 Materials by Metallic Fe and Ni Particles Additions". Materials 14 4 (2021): 980. http://dx.doi.org/10.3390/ma14040980.
    10.3390/ma14040980
  27. Okhay, Olena; Tkach, Alexander; Gallo, Maria J. Hortiguela; Otero-Irurueta, Gonzalo; Mikhalev, Sergey; Staiti, Pietro; Lufrano, Francesco. "Energy storage of supercapacitor electrodes on carbon cloth enhanced by graphene oxide aerogel reducing conditions". Journal of Energy Storage 32 (2020): 101839. http://dx.doi.org/10.1016/j.est.2020.101839.
    10.1016/j.est.2020.101839
  28. Arias-Serrano, Blanca I.; Mikhalev, Sergey M.; Ferro, Marta C.; Tobaldi, David M.; Frade, Jorge R.; Kovalevsky, Andrei V.. "On the high-temperature degradation mechanism of ZnO-based thermoelectrics". Journal of the European Ceramic Society (2020): http://dx.doi.org/10.1016/j.jeurceramsoc.2020.09.035.
    10.1016/j.jeurceramsoc.2020.09.035
  29. Loureiro, Francisco J.A.; Ramasamy, Devaraj; Mikhalev, Sergey M.; Shaula, Aliaksandr L.; Macedo, Daniel A.; Fagg, Duncan P.. "La4Ni3O10±d – BaCe0.9Y0.1O3-d cathodes for proton ceramic fuel cells; short-circuiting analysis using BaCe0.9Y0.1O3-d symmetric cells". International Journal of Hydrogen Energy (2020): http://dx.doi.org/10.1016/j.ijhydene.2020.06.243.
    10.1016/j.ijhydene.2020.06.243
  30. Kovalevsky, Andrei V.; Zakharchuk, Kiryl V.; Aguirre, Myriam H.; Xie, Wenjie; Patrício, Sonia G.; Ferreira, Nuno M.; Lopes, Diogo; et al. "Redox engineering of strontium titanate-based thermoelectrics". Journal of Materials Chemistry A 8 15 (2020): 7317-7330. http://dx.doi.org/10.1039/c9ta13824b.
    10.1039/c9ta13824b
  31. Arias-Serrano; Xie; Aguirre; Tobaldi; Sarabando; Rasekh; Mikhalev; et al. "Exploring Tantalum as a Potential Dopant to Promote the Thermoelectric Performance of Zinc Oxide". Materials 12 13 (2019): 2057. http://dx.doi.org/10.3390/ma12132057.
    10.3390/ma12132057
  32. Zakharchuk, Kiryl V.; Tobaldi, David M.; Xiao, Xingxing; Xie, Wenjie; Mikhalev, Sergey M.; Martins, João F.; Frade, Jorge R.; Weidenkaff, Anke; Kovalevsky, Andrei V.. "Synergistic effects of zirconium- and aluminum co-doping on the thermoelectric performance of zinc oxide". Journal of the European Ceramic Society 39 4 (2019): 1222-1229. http://dx.doi.org/10.1016/j.jeurceramsoc.2018.11.029.
    10.1016/j.jeurceramsoc.2018.11.029
  33. Loureiro, Francisco J. A.; Pérez-Coll, Domingo; Graça, Vanessa C. D.; Mikhalev, Sergey M.; Ribeiro, Alejandro F. G.; Mendes, Adélio; Fagg, Duncan P.. "Proton conductivity in yttrium-doped barium cerate under nominally dry reducing conditions for application in chemical synthesis". Journal of Materials Chemistry A 7 30 (2019): 18135-18142. http://dx.doi.org/10.1039/c9ta04584h.
    10.1039/c9ta04584h
  34. Nogueira, João; António, Maria; Mikhalev, Sergey; Fateixa, Sara; Trindade, Tito; Daniel-da-Silva, Ana. "Porous Carrageenan-Derived Carbons for Efficient Ciprofloxacin Removal from Water". Nanomaterials 8 12 (2018): 1004. http://dx.doi.org/10.3390/nano8121004.
    10.3390/nano8121004
  35. Shaula, A.L.; Karavai, O.V.; Ivanova, Yu.A.; Mikhalev, S.M.; Tarelho, L.A.C.. "Strontium ferrite as a three-way catalyst component". Materials Letters 216 (2018): 273-276. http://dx.doi.org/10.1016/j.matlet.2018.01.125.
    10.1016/j.matlet.2018.01.125
  36. Zakharchuk, Kiryl V.; Widenmeyer, Marc; Alikin, Denis O.; Xie, Wenjie; Populoh, Sascha; Mikhalev, Sergey M.; Tselev, Alexander; et al. "A self-forming nanocomposite concept for ZnO-based thermoelectrics". Journal of Materials Chemistry A 6 27 (2018): 13386-13396. http://dx.doi.org/10.1039/c8ta01463a.
    10.1039/c8ta01463a
  37. Kovalevsky, A.V.; Aguirre, M.H.; Populoh, S.; Patrício, S.G.; Ferreira, N.M.; Mikhalev, S.M.; Fagg, D.P.; Weidenkaff, A.; Frade, J.R.. "Designing strontium titanate-based thermoelectrics: insight into defect chemistry mechanisms". Journal of Materials Chemistry A 5 8 (2017): 3909-3922. http://www.scopus.com/inward/record.url?eid=2-s2.0-85013825352&partnerID=MN8TOARS.
    10.1039/c6ta09860f
  38. Antunes, I.; Mikhalev, S.; Mather, G.C.; Kharton, V.V.; Figueiras, F.G.; Alves, A.; Rodrigues, J.; et al. "Site Redistribution, Partial Frozen-in Defect Chemistry, and Electrical Properties of Ba1-x(Zr,Pr)O3-d". Inorganic Chemistry 55 17 (2016): 8552-8563. http://www.scopus.com/inward/record.url?eid=2-s2.0-84986220528&partnerID=MN8TOARS.
    10.1021/acs.inorgchem.6b01084
  39. Yang, T.; Shaula, A.L.; Mikhalev, S.M.; Ramasamy, D.; Fagg, D.P.. "Silver-praseodymium oxy-sulfate cermet: A new composite cathode for intermediate temperature solid oxide fuel cells". Journal of Power Sources 306 (2016): 611-616. http://www.scopus.com/inward/record.url?eid=2-s2.0-84958158334&partnerID=MN8TOARS.
    10.1016/j.jpowsour.2015.12.098
  40. Ferreira, N.M.; Ferro, M.C.; Mikhalev, S.M.; Costa, F.M.; Frade, J.R.; Kovalevsky, A.V.. "Guidelines to design multicomponent ferrospinels for high-temperature applications". RSC Advances 6 39 (2016): 32540-32548. http://www.scopus.com/inward/record.url?eid=2-s2.0-84964493048&partnerID=MN8TOARS.
    10.1039/c6ra03671f
  41. Ferreira, N.M.; Kovalevsky, A.V.; Mikhalev, S.M.; Costa, F.M.; Frade, J.R.. "Prospects and challenges of iron pyroelectrolysis in magnesium aluminosilicate melts near minimum liquidus temperature". Physical Chemistry Chemical Physics 17 14 (2015): 9313-9325. http://www.scopus.com/inward/record.url?eid=2-s2.0-84943590381&partnerID=MN8TOARS.
    10.1039/c5cp00858a
  42. Nasani, N.; Ramasamy, D.; Mikhalev, S.; Kovalevsky, A.V.; Fagg, D.P.. "Fabrication and electrochemical performance of a stable, anode supported thin BaCe0.4Zr0.4Y0.2O3-delectrolyte Protonic Ceramic Fuel Cell". Journal of Power Sources 278 (2015): 582-589. http://www.scopus.com/inward/record.url?eid=2-s2.0-84920179631&partnerID=MN8TOARS.
    10.1016/j.jpowsour.2014.12.124
  43. Kovalevsky, A.V.; Yaremchenko, A.A.; Naumovich, E.N.; Ferreira, N.M.; Mikhalev, S.M.; Costa, F.M.; Frade, J.R.. "Redox stability and high-temperature electrical conductivity of magnesium- and aluminium-substituted magnetite". Journal of the European Ceramic Society 33 13-14 (2013): 2751-2760. http://www.scopus.com/inward/record.url?eid=2-s2.0-84879840448&partnerID=MN8TOARS.
    10.1016/j.jeurceramsoc.2013.04.008
  44. Yaremchenko, A.A.; Mikhalev, S.M.; Kravchenko, E.S.; Frade, J.R.. "Thermochemical expansion of mixed-conducting (Ba,Sr)Co0.8Fe0.2O3-d ceramics". Journal of the European Ceramic Society (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84885780665&partnerID=MN8TOARS.
    10.1016/j.jeurceramsoc.2013.09.012
  45. Brando, A.D.; Antunes, I.; Frade, J.R.; Torre, J.; Mikhalev, S.M.; Fagg, D.P.. "Mechanochemical preparation, sintering aids and hybrid microwave sintering in the proton conductor Sr 0.02La 0.98Nb 1-xV xO 4-d, x = 0, 0.15". International Journal of Hydrogen Energy 37 8 (2012): 7252-7261. http://www.scopus.com/inward/record.url?eid=2-s2.0-84859212134&partnerID=MN8TOARS.
    10.1016/j.ijhydene.2011.12.041
  46. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Kinetics of the beryllium cathode reduction process. III. Non-stationary processes". Rasplavy 5 (2003): 76-83. http://www.scopus.com/inward/record.url?eid=2-s2.0-0348043540&partnerID=MN8TOARS.
  47. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Kinetics of the beryllium cathodic reduction process. I. Investigation of nature 'second wave' on polarization curves". Rasplavy 2 (2003): 29-40. http://www.scopus.com/inward/record.url?eid=2-s2.0-0037792925&partnerID=MN8TOARS.
  48. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Polarization of beryllium anode in fused mixtures (LiCl-KCl)eut-BeCl2. II. Nonstationary processes". Rasplavy 2 (2002): 30-34. http://www.scopus.com/inward/record.url?eid=2-s2.0-0036416346&partnerID=MN8TOARS.
  49. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Kinetics of the beryllium cathodic reduction process. II. Stationary processes". Rasplavy 5 (2002): 54-59. http://www.scopus.com/inward/record.url?eid=2-s2.0-0036909733&partnerID=MN8TOARS.
  50. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Polarization of beryllium anode in fused mixtures (LiCl-KCl)eut-BeCl2. I. Stationary processes". Rasplavy 2 (2002): 23-29. http://www.scopus.com/inward/record.url?eid=2-s2.0-0036412179&partnerID=MN8TOARS.
  51. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Polarization of beryllium anode in fused lithium and potassium chlorides eutectic. II. Non-stationary processes". Rasplavy 1 (2001): 10-13. http://www.scopus.com/inward/record.url?eid=2-s2.0-0035766407&partnerID=MN8TOARS.
  52. Rebrin, O.I.; Shcherbakov, R.Yu.; Mikhalev, S.M.. "Polarization of beryllium anode in molten lithium chloride - Potassium chloride eutectic. I. Stationary processes". Rasplavy 5 (2000): 70-78. http://www.scopus.com/inward/record.url?eid=2-s2.0-77949672495&partnerID=MN8TOARS.

Intellectual property

Patent
  1. Mikhalev, Sergey; Tao Yang; Fagg, D.P.; Shaula, A.L.. 2020. "A sulfate/sulfide based rechargeable battery and uses thereof".
    Granted/Issued
  2. SHAULA, ALIAKSANDR; Mikhalev, Sergey; Duncan Paul Fagg; Tao Yang. 2020. "European Patent - A sulfate/sulfide based rechargeable battery and uses thereof (EP3586385)".
    Granted/Issued
  3. Mikhalev, Sergey; Tao Yang; Fagg, Duncan; Shaula, A.L.. 2020. "European Patent : A sulfate/sulfide based rechargeable battery and uses thereof".
  4. Mikhalev, Sergey; Tao Yang; Fagg, D.P.; Shaula, A.L.. 2019. "A sulfate/sulfide based rechargeable battery and uses thereof". United States.
    Granted/Issued
  5. SHAULA, ALIAKSANDR; Mikhalev, Sergey; Duncan Paul Fagg; Tao Yang. 2019. "United States Patent - A sulfate/sulfide based rechargeable battery and uses thereof (US 2019/0379009)".
  6. Mikhalev, Sergey; Tao Yang; Fagg, D.P.; Shaula, A.L.. 2018. "A sulfate/sulfide based rechargeable battery and uses thereof".
    Granted/Issued
  7. SHAULA, ALIAKSANDR; Duncan Paul Fagg; Mikhalev, Sergey; Tao Yang. 2018. "International Patent - A sulfate/sulfide based rechargeable battery and uses thereof (WO/2018/154488)".
    Granted/Issued

Other

Data management plan
  1. Mikhalev, Sergey. "Github". 2024. . https://github.com/sergeMMikh/Eurotherm3200.
Other output
  1. Composition-, Temperature- and Pressure-Induced Transitions between High-Pressure Stabilized Perovskite Phases of the (1-X)Bife0.5sc0.5o3 - Xlafe0.5sc0.5o3 Series. 2023. Salak, A.N.; Cardoso, J.P.; Khalyavin, D.D.; Barbier, A.; Fertey, P.; Mikhalev, S.M.; Olekhnovich, N.M.; et al. http://www.scopus.com/inward/record.url?eid=2-s2.0-85147231519&partnerID=MN8TOARS.
    10.2139/ssrn.4341366
Spin-off company
  1. 2018. SEARCHPOTENTIAL. 72190 - Outra investigação e desenvolvimento das ciências físicas e naturais,.
Activities

Oral presentation

Presentation title Event name
Host (Event location)
2021/07/07 Antimony-lead melts for high temperature electrochemical applications 4th International Conference on Nanomaterials Science and Mechanical Engineering
University of Aveiro (Aveiro, Portugal)
2021/06 Anatase titania as magnesium host in Mg ion rechargeable battery with magnesium perchlorate / ethylmagnesium bromide electrolytes ANM2021 - Advanced Nanomaterials Conference,
Aveiro University (aveiro, Portugal)
2021/06 Magnesium hydride-added titania anode for Li-ion battery, 4th International Conference on Nanomaterials Science and Mechanical Engineering, (ICNMSME-2021).
Aveiro University (aveiro, Portugal)
2019 Proton conductivity in BCY10 in nominally dry reducing conditions 4th International Symposium on Materials for Energy Storage and Conversion (mESC-IS 2019)
(Akyaka, Mugla)
2018 Proton Ceramic Electrochemical Cells 14th International Conference on Advanced Nano Materials
(aveiro, Portugal)
2017 Protonic Ceramic Electrochemical Cells mESC-IS 2017, International Conference on Materials for Energy Storage and Conversion
(Cappadocia)

Supervision

Thesis Title
Role 		Degree Subject (Type)
Institution / Organization
2012 - 2016 Mechanochemistry of Materials for High Temperature Fuel Cells
Co-supervisor
 Science and Engineering of Materials (PhD)
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2011 - 2015 Extension of Electrochemically Active Sites in SOFCs and SOECs
Co-supervisor
 Nanosciences and Nanotechnology (PhD)
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2011 - 2015 CO2 tolerant materials for biogas fuel utilization
Co-supervisor
 Science and Engineering of Materials
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2011 - 2015 Electrolytes for Ceramic Oxide Fuel Cells
Co-supervisor
 Nanosciences and Nanotechnology
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2014 - 2014 Electrolytic Cells for Plastic Waste Recycling
Co-supervisor
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
2010 - 2014 Anodes for Protonic Ceramic Fuel Cells
Co-supervisor
 Nanosciences and Nanotechnology (PhD)
Universidade de Aveiro Centro de Tecnologia Mecânica e Automação, Portugal
Distinctions

Award

2017 CoHiTec Buisness School, one of eight teams selected for this training.
CoHiTec Buisness School , Portugal
2017 3rd Prize in ANI´s BFK2017 Innovation and Start-up Competition, Portugal (Phoenix team award together with Dr. Duncan Fagg and Dr. Yang Tao)
2017 The 1st Prize in the Songshan Lake Cup Innovation and Entrepreneurship Competition, European Division Finals (Phoenix team award together with Dr. Duncan Fagg and Dr. Yang Tao)
European Division Finals, Germany
1998 Stipendiary of the Ministry of Atomic Energy of Russian Federation.
Ural State Technical University - UPI, Russia