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Mário Vale holds a BSC. And MSc. in Technological Chemistry from the Faculty of Sciences, University of Lisbon. After finishing his master's, he worked as a researcher in Greenseal Research in the development of greener polyurethane foams. He then participated in a project with Cabopol to develop nanocomposites to enhance electrical cables' flame retardancy. Since 2018, he has been a Ph.D. Student in chemical engineering at Técnico. His Ph.D. research is focused on applying sol-gel chemistry in emulsions to create single and multicomponent oxide microspheres with customized porosity, known as MICROSCAFS. He is currently testing these new particles as photocatalytic supports in the Solar2Clean project.
Identificação

Identificação pessoal

Nome completo
Mário Filipe Lima do Vale
Género
Masculino

Nomes de citação

  • Vale, Mário

Identificadores de autor

Ciência ID
1D1F-1516-0649
ORCID iD
0000-0002-7986-9651
Researcher Id
AFS-4290-2022
Scopus Author Id
57192803831

Endereços de correio eletrónico

  • mario.vale@tecnico.ulisboa.pt (Profissional)
Formação
Grau Classificação
2018/09 - 2024/07
Em curso
Chemical Engineering (Doutoramento)
Universidade de Lisboa Instituto Superior Técnico, Portugal
"Engineered photocatalytic porous microspheres for water purification" (TESE/DISSERTAÇÃO)
2013/09 - 2015/12
Concluído
Technological Chemistry (Mestrado)
Universidade de Lisboa Faculdade de Ciências, Portugal
"Lignopolyol Based One-Component Polyurethane foams" (TESE/DISSERTAÇÃO)
17 valores
2009/09 - 2013/09
Concluído
Technological Chemistry (Licenciatura)
Especialização em Ramo de Processos e Produtos
Universidade de Lisboa Faculdade de Ciências, Portugal
14
Percurso profissional

Ciência

Categoria Profissional
Instituição de acolhimento
Empregador
2016/05 - 2017/01 Investigador (Investigação) Greenseal Research, Portugal
2014/09 - 2015/09 Estagiário de Investigação (Investigação) Greenseal Research, Portugal

Outros

Categoria Profissional
Instituição de acolhimento
Empregador
2017/03 - 2017/06 Research services provider Greenseal Research, Portugal
Projetos

Bolsa

Designação Financiadores
2024/04/01 - 2024/10/31 Engineered solar light driven photocatalytic systems for wastewater purification
PTDC/EQU-EQU/1056/2020
Bolseiro de Investigação
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal

Centro de Recursos Naturais e Ambiente, Portugal
Fundação para a Ciência e a Tecnologia
Em curso
2017/07 - 2018/09 Nanopoli: Nanocompósito resistente à chama
POCI-01-0247-FEDER-010228
Bolseiro de Investigação
European Regional Development Fund

Outro

Designação Financiadores
2019/01/01 - 2019/12/31 Center for Natural Resources and Environment
UID/ECI/04028/2019
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal

Centro de Recursos Naturais e Ambiente, Portugal

Universidade do Porto Faculdade de Engenharia, Portugal
Fundação para a Ciência e a Tecnologia
Concluído
Produções

Publicações

Artigo em revista
  1. Loureiro, M.V.; Mariquito, A.; Vale, M.; Bordado, J.C.; Pinho, I.; Marques, A.C.. "Emulsion Stabilization Strategies for Tailored Isocyanate Microcapsules". Polymers 15 2 (2023): http://www.scopus.com/inward/record.url?eid=2-s2.0-85146686395&partnerID=MN8TOARS.
    10.3390/polym15020403
  2. Vale, M.; Orišková, S.; Mariquito, A.; Reis, L.; Pinto, M.; Marques, A.C.. "Multicomponent oxide microspheres with designed macroporosity (MICROSCAFS®): a customized platform for chemicals immobilization". RSC Advances 13 19 (2023): 12951-12965. http://www.scopus.com/inward/record.url?eid=2-s2.0-85154595782&partnerID=MN8TOARS.
    10.1039/d3ra00895a
  3. Vale, M.; Marques, A.C.. "Mechanistic Study of the Formation of Multicomponent Oxide Porous Microspheres (MICROSCAFS®) by Cryo-Scanning Electron Microscopy". Gels 9 9 (2023): http://www.scopus.com/inward/record.url?eid=2-s2.0-85172226001&partnerID=MN8TOARS.
    10.3390/gels9090704
  4. Ana C. Marques; Mário Vale; Daniel Guilherme Henriques Vicente; Murielle Schreck; Elena Tervoort; Markus Niederberger. "Porous Silica Microspheres with Immobilized Titania Nanoparticles for In-Flow Solar-Driven Purification of Wastewater". Global Challenges 5 5 (2021): 2000116-2000116. http://dx.doi.org/10.1002/gch2.202000116.
    10.1002/gch2.202000116
  5. Marques, A.C.; Vale, M.. "Macroporosity control by phase separation in sol-gel derived monoliths and microspheres". Materials 14 15 (2021): http://www.scopus.com/inward/record.url?eid=2-s2.0-85112128331&partnerID=MN8TOARS.
    10.3390/ma14154247
  6. Vale, Mário. "The role played by different active hydrogen sources in the microencapsulation of a commercial oligomeric diisocyanate". Journal of Materials Science (2020): http://dx.doi.org/10.1007/s10853-019-04301-1.
    10.1007/s10853-019-04301-1
  7. Vale, Mário. "Silica-based microspheres with interconnected macroporosity by phase separation". Journal of Sol-Gel Science and Technology (2020): http://dx.doi.org/10.1007/s10971-020-05257-4.
    10.1007/s10971-020-05257-4
  8. Vale, Mário. "Polycaprolactone microcapsules containing citric acid and naringin for plant growth and sustainable agriculture: physico-chemical properties and release behavior". Science of The Total Environment (2020): http://dx.doi.org/10.1016/j.scitotenv.2019.135548.
    10.1016/j.scitotenv.2019.135548
  9. Loureiro, M.V.; Vale, M.; Galhano, R.; Matos, S.; Bordado, J.C.; Pinho, I.; Marques, A.C.. "Microencapsulation of Isocyanate in Biodegradable Poly(¿-caprolactone) Capsules and Application in Monocomponent Green Adhesives". ACS Applied Polymer Materials 2 11 (2020): 4425-4438. http://www.scopus.com/inward/record.url?eid=2-s2.0-85097540581&partnerID=MN8TOARS.
    10.1021/acsapm.0c00535
  10. Vale, Mário. "Hybrid shell microcapsules containing isophorone diisocyanate with high thermal and chemical stability for autonomous self-healing of epoxy coatings". Journal of Applied Polymer Science (2019): http://dx.doi.org/10.1002/app.48751.
    10.1002/app.48751
  11. Vale, Mário. "Replacement of petroleum-derived diols by sustainable biopolyols in one component polyurethane foams". Journal of Cleaner Production (2019): http://dx.doi.org/10.1016/j.jclepro.2018.12.088.
    10.1016/j.jclepro.2018.12.088
  12. Vale, Mário. "Isophorone Diisocyanate (IPDI) Microencapsulation for Mono-Component Adhesives: Effect of the Active H and NCO Sources". Polymers (2018): http://dx.doi.org/10.3390/polym10080825.
    10.3390/polym10080825
  13. Vale, Mário; Galhano dos Santos, R.; Acero, N.F.; Matos, S.; Carvalho, R.; Vale, M.; Marques, A.C.; Bordado, J.C.; Mateus, M.M.. "One-Component Spray Polyurethane Foam from Liquefied Pinewood Polyols: Pursuing Eco-Friendly Materials". Journal of Polymers and the Environment 26 1 (2018): 91-100. http://www.scopus.com/inward/record.url?eid=2-s2.0-85008197536&partnerID=MN8TOARS.
    https://doi.org/10.1007/s10924-016-0931-z
  14. Loureiro, M.V.; Vale, M.; De Schrijver, A.; Bordado, J.C.; Silva, E.; Marques, A.C.; Vale, Mário. "Hybrid custom-tailored sol-gel derived microscaffold for biocides immobilization". Microporous and Mesoporous Materials 261 (2018): 252-258. http://www.scopus.com/inward/record.url?eid=2-s2.0-85034756704&partnerID=MN8TOARS.
    10.1016/j.micromeso.2017.10.056
  15. Mateus, M.M.; do Vale, M.; Rodrigues, A.; Bordado, J.C.; Galhano dos Santos, R.; Vale, Mário. "Is biomass liquefaction an option for the viability of poplar short rotation coppices? A preliminary experimental approach". Energy 124 Supplement (2017): 40-45. http://www.scopus.com/inward/record.url?eid=2-s2.0-85013176784&partnerID=MN8TOARS.
    10.1016/j.energy.2017.02.059
Poster em conferência
  1. Vale, Mário. "PhD Open Days 2022". 2022.
  2. Vale, Mário; Marques, Ana C.. Autor correspondente: Vale, Mário. "Enlightenment of multicomponent oxide porous microspheres generation". Trabalho apresentado em Solgel 2022, 2022.
  3. Vale, Mário; Marques, Ana C.. "Engineered photocatalytic porous microspheres for water purification". Trabalho apresentado em Encontro Ciência 2022, 2022.
Atividades

Organização de evento

Nome do evento
Tipo de evento (Tipo de participação)
Instituição / Organização
2023/01 - Atual Member of the organizing committee and speaker in the Workshop TPMI 2023 organized by the Technological Platform on Microencapsulation and Immobilization (TPMI) at Instituto Superior Técnico, Lisbon, Portugal. The workshop was about the fundamentals and applications of encapsulation and immobilization using polymerization and sol-gel. (2023/05)
Oficina (workshop) (Membro da Comissão Organizadora)

Participação em evento

Descrição da atividade
Tipo de evento
Nome do evento
Instituição / Organização
2022/07 - Atual Workshop Photonic glasses by sol-gel organized by the International Sol-Gel Society (ISGS) and the International Commission on Glass (ICG) during the SOLGEL 2022 conference at Lyon, France. This event treated with the state of the art on the fundamentals, preparation and characterization of materials obtained by sol-gel with important photonic applications.
2018/09/06 - 2018/09/08 Escola Ibero-Americana de Catálise (EICat 2018) where theoretical and practical classes were taught by specialists from Portugal, Spain and Brazil in the area of heterogeneous catalysis. The topics covered were: catalyst synthesis, textural and structural characterization, thermal analysis (TG / DSC; TPR), characterization by spectroscopy (Raman, FTIR and UV-Vis), temperature programmed reduction, scanning electron microscopy and kinetic modeling.
Oficina (workshop)
Escola Ibero-Americana de Catálise (EICat 2018)
Universidade de Lisboa Instituto Superior Técnico, Portugal
2017/07/03 - 2017/07/05 Demonstrator of "Technological Platform on Microencapsulation and Immobilization" at the Ciência 2017 meeting, representing Center for Natural Resources and the Environment (CERENA) and the Instituto Superior Técnico. The event was intended to promote a wide-ranging debate on the main themes and challenges of the scientific agenda in Portugal.
Encontro
Ciência 2017
Governo da República Portuguesa Ministério da Ciência Tecnologia e Ensino Superior, Portugal

Fundação para a Ciência e a Tecnologia, Portugal

Ciência Viva, Portugal

Assembleia da República, Portugal