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Identificação

Identificação pessoal

Nome completo
José do Rosário Ascenso

Nomes de citação

  • Ascenso, J.R.

Identificadores de autor

Ciência ID
991C-F098-638F
ORCID iD
0000-0002-5535-2500
Formação
Grau Classificação
2007
Concluído
 Química (Título de Agregado)
Universidade de Lisboa Instituto Superior Técnico, Portugal
 Unanimidade
1967 - 2002
Concluído
 Engenharia Química (Licenciatura)
Universidade de Lisboa Instituto Superior Técnico, Portugal
 Unanimidade
1985
Concluído
 Chemistry (Pós-doutoramento)
Especialização em Solid State Nuclear Magnetic Resonance
Durham University, Reino Unido
1977 - 1981
Concluído
 José Rosário Ascenso (Doutoramento)
Especialização em Ressonância Magnética Nuclear
Universidade de Lisboa Instituto Superior Técnico, Portugal
"NMR Studies of LnEDTA Anions as probes for Structural Studies" (TESE/DISSERTAÇÃO)
 Distinção e Louvor
Percurso profissional

Docência no Ensino Superior

Categoria Profissional
Instituição de acolhimento 		Empregador
1989 - Atual Professor Associado (Docente Universitário) Universidade de Lisboa Instituto Superior Técnico, Portugal
1981 - 1989 Professor Auxiliar (Docente Universitário) Universidade de Lisboa Instituto Superior Técnico, Portugal
1972 - 1980 Assistente (Docente Universitário) Universidade de Lisboa Instituto Superior Técnico, Portugal
Projetos

Projeto

Designação Financiadores
2017 - 2021 Projecto de Infraestruturas de Investigação nº 22161 PTNMR
AAC 01/SAICT/2016.
Investigador
Universidade Nova de Lisboa Faculdade de Ciências e Tecnologia, Portugal
Em curso
2013 - 2017 From drug design to new materials: structural approach in emergent fields
RECI/QEQ-QIN/0189/2012
Investigador
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2009 - 2011 ovel highly-tunable carbene complexes with catalytic, biological and photophysical properties
PTDC/QUI-QUI/098760/2008.
Investigador
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2007 - 2010 Synthesis of new homooxacalixarene based anion receptors
PTDC/QUI/69858/2006
Investigador
Fundação da Faculdade de Ciências da Universidade de Lisboa, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2007 - 2009 Single Molecule Signalling of Peptide Metal Bindind
PTDC/QUI/64658/2006
Investigador
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2007 - 2009 Synthesis of Organometallic Molecular and Polymeric Materials with NLO Properties
PTDC/QUI/64658/2006
Investigador
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2007 - 2009 Paramagnetic and cationic Ti and U bis(phenoxide) diamine complexes: synthesis and reactivity. Applications in C-C bond forming by electron-transfer reactions.
PTDC/QUI/66187/2006
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2004 - 2007 -Síntese e Aplicações Catalíticas de Complexos dos Grupos 4 e 5 Suportados por Tetra-azamacrocíclos
POCI/QUI/55744/2004
Investigador
Associação para a Inovação e Desenvolvimento da FCT
Concluído
2004 - 2007 Novos Catalizadores Organometálicos Contendo Ligandos Imino-pirrolilo e Análogos para Oligomerização e Polimerização de Olefinas
POCI/QUI/59025/2004
Investigador
Universidade de Lisboa Instituto Superior Técnico, Portugal
Concluído
2004 - 2007 Novos Catalizadores Organometálicos Contendo Ligandos Imino-pirrolilo e Análogos para Oligomerização e Polimerização de Olefinas
POCI/QUI/59025/2004
 N/A
2002 - 2005 Caracterização Estrutural e Estudos de Reactividade por Ressonância Magnética Nuclear, Programa Nacional de Reequipamento,
CONC-REEQ/QUI/103/2002
Investigador responsável
Associação para a Inovação e Desenvolvimento da FCT
Concluído
2002 - 2005 Mono and Dianionic Triazacyclononane Based Ligands as Ancilaries in Lanthanide and Transition Metal Chemistry
POCTI/QUI/46206/2002
Investigador
Associação para a Inovação e Desenvolvimento da FCT
Concluído
2002 - 2005 Triazamacrocycle Based Tris-amido-Tris-amine Transition Metal Complexes: Synthesis, Reactivity and Structure.
POCTI/QUI/39734/2001
Investigador
Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2002 - 2005 Mono and Dianionic Triazacyclononane Based Ligands as Ancilaries in Lanthanide and Transition Metal Chemistry
POCTI/QUI/46206/2002
 Associação para a Inovação e Desenvolvimento da FCT
2000 - 2002 Synthesis of Organometallic Complexesof Transition Metals to be used as Catalysts in the Polymerization of Olefins/Polar Vinyl Monomers
POCTI/QUI/32771/99
Investigador
Universidade de Lisboa Instituto Superior Técnico, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
2000 - 2002 Synthesis and Characterization of Polynuclear Organometallic Compounds with Potential Non-Linear Optical (NLO) Properties
POCTI/QUI/354197/99
Investigador
Universidade de Lisboa Instituto Superior Técnico, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
1997 - 1999 Homo, Co-e-Terp-Polimerização de Etileno/Propileno/d-Olefinas Contendo Grupos Hidrófilos usando Catalizadores do Tipo Ziegler-Natta, Estudo e Modelização Cinética
Praxis/PCEX/C/QUI/77/96
Concluído
1995 - 1997 Síntese de Complexos de Metais de Transição com Ligandos Ciclopentadienilo e Análogos. Aplicações em Catálise e Novos Materiais
2/2.1/QUI/143/9
Investigador
Universidade de Lisboa Instituto Superior Técnico, Portugal
 Associação para a Inovação e Desenvolvimento da FCT
Concluído
Produções

Publicações

Artigo em conferência
  1. Ascenso, José R.; Fareleira, João M. N. A.; Rubio, Guilherme; Martins, Luís A. M.; Diogo, João C. F.; Caetano, Fernando J. P.. "On the mobility of dialkyl adipates by PFGSE NMR, computer simulations and other property measurement methods". 2014.
  2. Ascenso, J.R.. "On the mobility of ionic liquids by PFGSE NMR and other property measurement methods". Trabalho apresentado em IV Ibero-American NMR Meeting, Aveiro, 2012.
Artigo em revista
  1. Alexandre Santos Miranda; Paula M. Marcos; Ascenso J.R.; M. Paula Robalo; Vasco D. B. Bonifácio; Mario Berberan-Santos; Neal Hickey; Silvano Geremia. "Conventional vs. Microwave- or Mechanically-Assisted Synthesis of Dihomooxacalix[4]arene Phthalimides: NMR, X-ray and Photophysical Analysis". Molecules (2021): https://www.mdpi.com/1420-3049/26/6/1503.
    10.3390/molecules26061503
  2. Ascenso, José. "Dihomooxacalix[4]arene-Based Fluorescent Receptors for Anion and Organic Ion Pair Recognition". molecules (2020):
    10.3390/molecules25204708
  3. Franco, A.; Ascenso, J.R.; Ilharco, L.; Da Silva, J.A.L.. "Synthesis of ribonucleotides from the corresponding ribonucleosides under plausible prebiotic conditions within self-assembled supramolecular structures". New Journal of Chemistry 44 6 (2020): 2206-2209. http://www.scopus.com/inward/record.url?eid=2-s2.0-85079409293&partnerID=MN8TOARS.
    10.1039/c9nj05601g
  4. Teixeira, F.A.; Ascenso, J.R.; Cragg, P.J.; Hickey, N.; Geremia, S.; Marcos, P.M.. "Recognition of Anions, Monoamine Neurotransmitter and Trace Amine Hydrochlorides by Ureido-Hexahomotrioxacalix[3]arene Ditopic Receptors". European Journal of Organic Chemistry 2020 13 (2020): 1930-1940. http://www.scopus.com/inward/record.url?eid=2-s2.0-85082871252&partnerID=MN8TOARS.
    10.1002/ejoc.201901888
  5. Ascenso, José. "Ribose-borate esters as potential components for prebiological evolution". (2019): http://dx.doi.org/10.1016/j.molstruc.2019.02.031.
    10.1016/j.molstruc.2019.02.031
  6. Singh, M.; Singh, N.; Ascenso, J.R.; Marcos, P.M.. "A Dihomooxacalix[4]arene-gold nanohybrid based colorimetric sensor for sensitive and selective detection of iodide". Supramolecular Chemistry 31 5 (2019): 313-321. http://www.scopus.com/inward/record.url?eid=2-s2.0-85064652316&partnerID=MN8TOARS.
    10.1080/10610278.2019.1575380
  7. Miranda, A.S.; Serbetci, D.; Marcos, P.M.; Ascenso, J.R.; Berberan-Santos, M.N.; Hickey, N.; Geremia, S.. "Ditopic Receptors Based on Dihomooxacalix[4]arenes Bearing Phenylurea Moieties With Electron-Withdrawing Groups for Anions and Organic Ion Pairs". Frontiers in Chemistry 7 (2019): http://www.scopus.com/inward/record.url?eid=2-s2.0-85075642667&partnerID=MN8TOARS.
    10.3389/fchem.2019.00758
  8. Fonseca, J.D.; Marcos, P.M.; Ascenso, J.R.; Michel, S.; Hubscher-Bruder, V.; Schurhammer, R.. "Extraction and complexation of lanthanide ions by dihomooxacalix[4]arene and calix[4]arene tetraketone derivatives: An experimental and molecular dynamics investigation,Extraction et complexation d'ions lanthanide par des dérivés tétracétone du dihomooxacalix[4]arène et du calix[4]arène: étude expérimentale et dynamique moléculaire". Comptes Rendus Chimie 22 9-10 (2019): 639-647. http://www.scopus.com/inward/record.url?eid=2-s2.0-85073160996&partnerID=MN8TOARS.
    10.1016/j.crci.2019.09.005
  9. Ana S. Augusto; Alexandre S. Miranda; José R. Ascenso; Margarida Q. Miranda; Vítor Félix; Giovanna Brancatelli; Neal Hickey; Silvano Geremia; Paula M. Marcos. "Anion Recognition by Partial Cone Dihomooxacalix[4]arene-Based Receptors Bearing Urea Groups: Remarkable Affinity for Benzoate Ion". European Journal of Organic Chemistry 2018 41 (2018): 5657-5667. https://doi.org/10.1002/ejoc.201800880.
    10.1002/ejoc.201800880
  10. Ascenso, José. "Synthesis and Characterization of Isosorbide-Based Polyurethanes Exhibiting Low Cytotoxicity Towards HaCaT Human Skin Cells". (2018): http://dx.doi.org/10.3390/polym10101170.
    10.3390/polym10101170
  11. Tiago F. C. Cruz; Pedro M. M. Machado; Clara S. B. Gomes; José R. Ascenso; M. Amélia N. D. A. Lemos; João C. Bordado; Pedro T. Gomes. "Bis(formylpyrrolyl) cobalt complexes as mediators in the reversible-deactivation radical polymerization of styrene and methyl methacrylate". New Journal of Chemistry (2018): https://doi.org/10.1039/C8NJ00350E.
    10.1039/C8NJ00350E
  12. Cruz, T.F.C.; Machado, P.M.M.; Gomes, C.S.B.; Ascenso, J.R.; Lemos, M.A.N.D.A.; Bordado, J.C.; Gomes, P.T.. "Bis(formylpyrrolyl) cobalt complexes as mediators in the reversible-deactivation radical polymerization of styrene and methyl methacrylate". New Journal of Chemistry 42 8 (2018): 5900-5913. http://www.scopus.com/inward/record.url?eid=2-s2.0-85045542179&partnerID=MN8TOARS.
    10.1039/c8nj00350e
  13. Teixeira, F.A.; Marcos, P.M.; Ascenso, J.R.; Brancatelli, G.; Hickey, N.; Geremia, S.. "Selective Binding of Spherical and Linear Anions by Tetraphenyl(thio)urea-Based Dihomooxacalix[4]arene Receptors". Journal of Organic Chemistry 82 21 (2017): 11383-11390. http://www.scopus.com/inward/record.url?eid=2-s2.0-85032803825&partnerID=MN8TOARS.
    10.1021/acs.joc.7b01801
  14. Ascenso, J.R.; Rubio, G.; Diogo, J.C.F.; Avelino, H.M.N.T.; Caetano, F.J.P.; Fareleira, J.M.N.A.. "Self-diffusivity measurements of dimethyl, diethyl, dipropyl, dibutyl, Bis(2-ethylhexyl) adipates from (293-339) K by a PGSE-NMR spin-echo technique". Fluid Phase Equilibria 410 (2016): 37-41. http://www.scopus.com/inward/record.url?eid=2-s2.0-84949666220&partnerID=MN8TOARS.
    10.1016/j.fluid.2015.11.020
  15. Marcos, P.M.; Fonseca, J.D.; Proença, C.S.; Ascenso, J.R.; Bernardino, R.J.; Kulesza, J.; Bochenska, M.. "Experimental and computational studies of the binding properties of lower rim tetra- and di-substituted calix[4]arene amide derivatives with metal ions". Supramolecular Chemistry 28 5-6 (2016): 367-376. http://www.scopus.com/inward/record.url?eid=2-s2.0-84958054049&partnerID=MN8TOARS.
    10.1080/10610278.2015.1093631
  16. Pimenta, A.F.R.; Ascenso, J.; Fernandes, J.C.S.; Colaço, R.; Serro, A.P.; Saramago, B.. "Controlled drug release from hydrogels for contact lenses: Drug partitioning and diffusion". International Journal of Pharmaceutics 515 1-2 (2016): 467-475. http://www.scopus.com/inward/record.url?eid=2-s2.0-84993961089&partnerID=MN8TOARS.
    10.1016/j.ijpharm.2016.10.047
  17. Talotta, C.; Gaeta, C.; De Rosa, M.; Ascenso, J.R.; Marcos, P.M.; Neri, P.. "Alkylammonium Guest Induced-Fit Recognition by a Flexible Dihomooxacalix[4]arene Derivative". European Journal of Organic Chemistry 2016 1 (2016): 158-167. http://www.scopus.com/inward/record.url?eid=2-s2.0-84954549919&partnerID=MN8TOARS.
    10.1002/ejoc.201501319
  18. Martínez-González, E.; González, F.J.; Ascenso, J.R.; Marcos, P.M.; Frontana, C.. "Competition between Hydrogen Bonding and Proton Transfer during Specific Anion Recognition by Dihomooxacalix[4]arene Bidentate Ureas". Journal of Organic Chemistry 81 15 (2016): 6329-6335. http://www.scopus.com/inward/record.url?eid=2-s2.0-84981194457&partnerID=MN8TOARS.
    10.1021/acs.joc.6b00962
  19. Martínez-González, E.; Armendáriz-Vidales, G.; Ascenso, J.R.; Marcos, P.M.; Frontana, C.. "Site-specific description of the enhanced recognition between electrogenerated nitrobenzene anions and dihomooxacalix[4]arene bidentate ureas". Journal of Organic Chemistry 80 9 (2015): 4581-4589. http://www.scopus.com/inward/record.url?eid=2-s2.0-84928911571&partnerID=MN8TOARS.
    10.1021/acs.joc.5b00441
  20. Martins, L.F.G.; Pereira, L.A.M.; Silva, G.M.C.; Ascenso, J.R.; Morgado, P.; Ramalho, J.P.P.; Filipe, E.J.M.. "Fluorinated surfactants in solution: Diffusion coefficients of fluorinated alcohols in water". Fluid Phase Equilibria 407 (2015): 322-333. http://www.scopus.com/inward/record.url?eid=2-s2.0-84945437842&partnerID=MN8TOARS.
    10.1016/j.fluid.2015.06.006
  21. Silva, F.; Campello, M.P.C.; Gano, L.; Fernandes, C.; Santos, I.; Santos, I.C.; Ascenso, J.R.; João Ferreira, M.; Paulo, A.. "Chemical, radiochemical and biological studies of new gallium(iii) complexes with hexadentate chelators". Dalton Transactions 44 7 (2015): 3342-3355. http://www.scopus.com/inward/record.url?eid=2-s2.0-84922643996&partnerID=MN8TOARS.
    10.1039/c4dt02274b
  22. Gattuso, G.; Notti, A.; Parisi, M.F.; Pisagatti, I.; Marcos, P.M.; Ascenso, J.R.; Brancatelli, G.; Geremia, S.. "Selective recognition of biogenic amine hydrochlorides by heteroditopic dihomooxacalix[4]arenes". New Journal of Chemistry 39 2 (2015): 817-821. http://www.scopus.com/inward/record.url?eid=2-s2.0-84922569255&partnerID=MN8TOARS.
    10.1039/c4nj01423e
  23. Pereira, L.A.M.; Martins, L.F.G.; Ascenso, J.R.; Morgado, P.; Ramalho, J.P.P.; Filipe, E.J.M.. "Diffusion coefficients of fluorinated surfactants in water: Experimental results and prediction by computer simulation". Journal of Chemical and Engineering Data 59 10 (2014): 3151-3159. http://www.scopus.com/inward/record.url?eid=2-s2.0-84907886215&partnerID=MN8TOARS.
    10.1021/je500211w
  24. Marcos, P.M.; Teixeira, F.A.; Segurado, M.A.P.; Ascenso, J.R.; Bernardino, R.J.; Brancatelli, G.; Geremia, S.. "Synthesis and anion binding properties of new dihomooxacalix[4]arene diurea and dithiourea receptors". Tetrahedron 70 37 (2014): 6497-6505. http://www.scopus.com/inward/record.url?eid=2-s2.0-84949115179&partnerID=MN8TOARS.
    10.1016/j.tet.2014.07.020
  25. Bernardes, C.E.S.; Lopes, M.L.S.M.; Ascenso, J.R.; Da Piedade, M.E.M.. "From molecules to crystals: The solvent plays an active role throughout the nucleation pathway of molecular organic crystals". Crystal Growth and Design 14 11 (2014): 5436-5441. http://www.scopus.com/inward/record.url?eid=2-s2.0-84908691502&partnerID=MN8TOARS.
    10.1021/cg500609g
  26. Griffiths, K.; Sharma, K.; Marcos, P.M.; Ascenso, J.R.; Nind, J.; Cottet, K.; Cragg, P.J.. "Cation binding, transport and theoretical calculations of cone-p-tert-butylhexahomotrioxacalix[3]arene tris(acetic acid)". Supramolecular Chemistry (2014): http://www.scopus.com/inward/record.url?eid=2-s2.0-84902302349&partnerID=MN8TOARS.
    10.1080/10610278.2014.918269
  27. Marcos, P.M.; Teixeira, F.A.; Segurado, M.A.P.; Ascenso, J.R.; Bernardino, R.J.; Michel, S.; Hubscher-Bruder, V.. "Bidentate urea derivatives of p-tert-butyldihomooxacalix[4]arene: Neutral receptors for anion complexation". Journal of Organic Chemistry 79 2 (2014): 742-751. http://www.scopus.com/inward/record.url?eid=2-s2.0-84896801891&partnerID=MN8TOARS.
    10.1021/jo4026012
  28. Lourenço, A.B.; Roque, F.C.; Teixeira, M.C.; Ascenso, J.R.; Sá-Correia, I.. "Quantitative 1H-NMR-Metabolomics Reveals Extensive Metabolic Reprogramming and the Effect of the Aquaglyceroporin FPS1 in Ethanol-Stressed Yeast Cells". PLoS ONE 8 2 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84873621089&partnerID=MN8TOARS.
    10.1371/journal.pone.0055439
  29. Matos, I.; Ascenso, J.R.; Lemos, M.; Fan, Z.; Yuan, J.; Farinha, J.P.S.; Lemos, F.; Gonçalves Da Silva, A.M.P.S.; Marques, M.M.. "Structure, morphology and interfacial behaviour of ethylene/methacrylate copolymers". Journal of Polymer Research 20 3 (2013): http://www.scopus.com/inward/record.url?eid=2-s2.0-84873386414&partnerID=MN8TOARS.
    10.1007/s10965-013-0090-z
  30. Marcos, P.M.; Proença, C.S.; Teixeira, F.A.; Ascenso, J.R.; Bernardino, R.J.; Cragg, P.J.. "Synthesis, NMR and DFT conformational studies of homooxacalixarene (cyanopropyl)oxy derivatives, precursors to urea-terminated compounds". Tetrahedron 69 35 (2013): 7430-7437. http://www.scopus.com/inward/record.url?eid=2-s2.0-84880734817&partnerID=MN8TOARS.
    10.1016/j.tet.2013.06.048
  31. Marcos, P.M.; Teixeira, F.A.; Segurado, M.A.P.; Ascenso, J.R.; Bernardino, R.J.; Cragg, P.J.; Michel, S.; Hubscher-Bruder, V.; Arnaud-Neu, F.. "Complexation and DFT studies of lower rim hexahomotrioxacalix[3]arene derivatives bearing pyridyl groups with transition and heavy metal cations. Cone versus partial cone conformation". Journal of Physical Organic Chemistry 26 4 (2013): 295-305. http://www.scopus.com/inward/record.url?eid=2-s2.0-84875491317&partnerID=MN8TOARS.
    10.1002/poc.3085
  32. Marcos, P.M.; Teixeira, F.A.; Segurado, M.A.P.; Ascenso, J.R.; Bernardino, R.J.; Cragg, P.J.; Michel, S.; Hubscher-Bruder, V.; Arnaud-Neu, F.. "Complexation and DFT studies of lanthanide ions by (2-pyridylmethoxy) homooxacalixarene derivatives". Supramolecular Chemistry 25 8 (2013): 522-532. http://www.scopus.com/inward/record.url?eid=2-s2.0-84882454409&partnerID=MN8TOARS.
    10.1080/10610278.2013.801556
  33. Gaeta, C.; Talotta, C.; Farina, F.; Teixeira, F.A.; Marcos, P.M.; Ascenso, J.R.; Neri, P.. "Alkylammonium cation complexation into the narrow cavity of dihomooxacalix[4]arene macrocycle". Journal of Organic Chemistry 77 22 (2012): 10285-10293. http://www.scopus.com/inward/record.url?eid=2-s2.0-84869179671&partnerID=MN8TOARS.
    10.1021/jo3019945
  34. Ferreira, J.A.B.; Sánchez-Coronilla, A.; Togashi, D.M.; Ferreira, H.; Ascenso, J.R.; Costa, S.M.B.. "Electrophilic reactivity of tetrabromorhodamine 123 is bromine induced: Convergent interpretation through complementary molecular descriptors". Journal of Physical Chemistry A 116 48 (2012): 11938-11945. http://www.scopus.com/inward/record.url?eid=2-s2.0-84870807140&partnerID=MN8TOARS.
    10.1021/jp307461m
  35. Antunes, M.A.; Alves, L.G.; Namorado, S.; Ascenso, J.R.; Veiros, L.F.; Martins, A.M.. "Hydride abstraction from [MCp Bz(CO) 3H] (M = Mo, W; Cp Bz = C 5(CH 2Ph) 5): New cationic complexes stabilized by ¿ 5:¿ 2-C 5H 4:C 6H 5 bonding of the pentabenzylcyclopentadienyl ligand". Organometallics 31 12 (2012): 4387-4396. http://www.scopus.com/inward/record.url?eid=2-s2.0-84862731019&partnerID=MN8TOARS.
    10.1021/om300070m
  36. Lourenço, A.B.; Ascenso, J.R.; Sá-Correia, I.. "Metabolic insights into the yeast response to propionic acid based on high resolution 1H NMR spectroscopy". Metabolomics 7 4 (2011): 457-468. http://www.scopus.com/inward/record.url?eid=2-s2.0-80054010207&partnerID=MN8TOARS.
    10.1007/s11306-010-0264-1
  37. Marcos, P.M.; Ascenso, J.R.; Segurado, M.A.P.; Cragg, P.J.; Michel, S.; Hubscher-Bruder, V.; Arnaud-Neu, F.. "Lanthanide cation binding properties of homooxacalixarene diethylamide derivatives". Supramolecular Chemistry 23 1-2 (2011): 93-101. http://www.scopus.com/inward/record.url?eid=2-s2.0-79952235201&partnerID=MN8TOARS.
    10.1080/10610278.2010.510562
  38. Li, L.; Gomes, C.S.B.; Lopes, P.S.; Gomes, P.T.; Diogo, H.P.; Ascenso, J.R.. "Polymerization of styrene with tetradentate chelated a-diimine nickel(II) complexes/MAO catalyst systems: Catalytic behavior and microstructure of polystyrene". European Polymer Journal 47 8 (2011): 1636-1645. http://www.scopus.com/inward/record.url?eid=2-s2.0-79961170331&partnerID=MN8TOARS.
    10.1016/j.eurpolymj.2011.05.015
  39. Augusta Antunes, M.; Namorado, S.; de Azevedo, C.G.; Amélia Lemos, M.; Teresa Duarte, M.; Ascenso, J.R.; Martins, A.M.. "Pentabenzylcyclopentadienyl molybdenum and tungsten hydrides: Syntheses, structures and electrochemistry of [MHCpBz(CO)2(L)] (L = CO, PMe3, PPh3)". Journal of Organometallic Chemistry 695 9 (2010): 1328-1336. http://www.scopus.com/inward/record.url?eid=2-s2.0-77950188557&partnerID=MN8TOARS.
    10.1016/j.jorganchem.2010.02.012
  40. Matos, I.; Fernandes, A.; Catalão, R.; Dptelh Do Rego, A.M.; Ascenso, J.R.; Fonseca, I.F.; Lemos, F.; Marques, M.M.. "Heterogeneization of alpha diimines nickel catalysts for the polymerization of ethylene and methylmethacrylate". E-Polymers (2010): http://www.scopus.com/inward/record.url?eid=2-s2.0-79751482250&partnerID=MN8TOARS.
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    10.1016/S0040-4020(99)00471-8
  93. Paulo, A.; Ascenso, J.; Domingos, Â.; Galvão, A.; Santos, I.. "Rhenium-(III) and -(V) hydride complexes with modified poly(pyrazolyl)borates". Journal of the Chemical Society - Dalton Transactions 8 (1999): 1293-1300. http://www.scopus.com/inward/record.url?eid=2-s2.0-33748820134&partnerID=MN8TOARS.
  94. Marques, M.M.; Correia, S.G.; Ascenso, J.R.; Ribeiro, A.F.G.; Gomes, P.T.; Dias, A.R.; Foster, P.; Rausch, M.D.; Chien, J.C.W.. "Polymerization with TMA-protected polar vinyl comonomers. I. Catalyzed by group 4 metal complexes with irj5-type ligands". Journal of Polymer Science, Part A: Polymer Chemistry 37 14 (1999): 2457-2469. http://www.scopus.com/inward/record.url?eid=2-s2.0-85087245140&partnerID=MN8TOARS.
    10.1002/(sici)1099-0518(19990715)37:14<2457::aid-pola20>3.3.co;2-p
  95. Gigante, B.; Esteves, M.A.; Curto, M.J.M.; Ascenso, J.; Prabhakar, S.; Lobo, A.M.. "New resin acid derivatives: Diisocyanate, diurethanes and diureides". Synthetic Communications 28 4 (1998): 639-652. http://www.scopus.com/inward/record.url?eid=2-s2.0-0031950989&partnerID=MN8TOARS.
  96. Ferreira, M.-J.U.; Madureira, A.M.; Ascenso, J.R.. "A tetracyclic diterpene and triterpenes from Euphorbia segetalis". Phytochemistry 49 1 (1998): 179-183. http://www.scopus.com/inward/record.url?eid=2-s2.0-0031670143&partnerID=MN8TOARS.
    10.1016/S0031-9422(97)01011-X
  97. Félix, S.; Ascenso, J.R.; Lamartine, R.; Pereira, J.L.C.. "Inherently chiral calixcrowns derived from p-tert- butyldihomooxacalix[4]arene". Synthetic Communications 28 10 (1998): 1793-1799. http://www.scopus.com/inward/record.url?eid=2-s2.0-1942484112&partnerID=MN8TOARS.
  98. Marcos, P.M.; Ascenso, J.R.; Lamartine, R.; Pereira, J.L.C.. "Synthesis and Conformational Characteristics of Inherently Chiral Monoalkyl Ethers of p-tert-Butyldihomooxacalix[4]arene". Journal of Organic Chemistry 63 1 (1998): 69-74. http://www.scopus.com/inward/record.url?eid=2-s2.0-0001939291&partnerID=MN8TOARS.
  99. Justino, J.; Dias, A.R.; Ascenso, J.; Marques, M.M.; Tait, P.J.T.. "Polymerization of ethylene using metallocene and aluminoxane systems". Polymer International 44 4 (1997): 407-412. http://www.scopus.com/inward/record.url?eid=2-s2.0-0031366772&partnerID=MN8TOARS.
  100. Marcos, P.M.; Ascenso, J.R.; Lamartine, R.; Pereira, J.L.C.. "NMR conformational studies of tetraalkylated dihomooxacalix[4]arenes". Tetrahedron 53 34 (1997): 11791-11802. http://www.scopus.com/inward/record.url?eid=2-s2.0-0030802405&partnerID=MN8TOARS.
    10.1016/S0040-4020(97)00753-9
  101. Ascenso, J.R.; Ferreira, M.J.U.. "Assignment of carbon-13 and proton nuclear magnetic resonance spectra of madeirane triterpenes". Magnetic Resonance in Chemistry 35 9 (1997): 643-646. http://www.scopus.com/inward/record.url?eid=2-s2.0-0031519495&partnerID=MN8TOARS.
  102. Justino, J.; Dias, A.R.; Ascenso, J.; Marques, M.M.; Tait, P.J.T.. "Polymerization of ethylene using metallocene and aluminoxane systems". Polymer International 44 4 (1997): 407-412. http://www.scopus.com/inward/record.url?eid=2-s2.0-85087581712&partnerID=MN8TOARS.
    10.1002/(sici)1097-0126(199712)44:4<407::aid-pi844>3.3.co;2-t
  103. Ferreira, M.J.U.; Duarte, A.; Ascenso, J.R.. "Antimicrobial activity and phytochemical study of Euphorbia tuckeyana". Fitoterapia 67 1 (1996): 85-86. http://www.scopus.com/inward/record.url?eid=2-s2.0-0029866969&partnerID=MN8TOARS.
  104. Ascenso, J.R.; Gonçalves, I.S.; Herdtweck, E.; Romão, C.C.. "Ring slippage in indenyl derivatives of molybdenum and tungsten". Journal of Organometallic Chemistry 508 1-2 (1996): 169-181. http://www.scopus.com/inward/record.url?eid=2-s2.0-0030574602&partnerID=MN8TOARS.
  105. Ascenso, J.R.; Dias, A.R.; Gomes, P.T.; Romão, C.C.; Tkatchenko, I.; Revillon, A.; Pham, Q.-T.. "Isospecific oligo-/Polymerization of styrene with soluble cationic nickel complexes. the influence of phosphorus(III) ligands". Macromolecules 29 12 (1996): 4172-4179. http://www.scopus.com/inward/record.url?eid=2-s2.0-0030567643&partnerID=MN8TOARS.
  106. Marcos, P.M.; Ascenso, J.R.; Lamartine, R.; Pereira, J.L.C.. "Synthesis and NMR conformational studies of p-tert-butyldihomooxacalix[4]-arene derivatives". Supramolecular Chemistry 6 3-4 (1996): 303-306. http://www.scopus.com/inward/record.url?eid=2-s2.0-0013565849&partnerID=MN8TOARS.
  107. Tavares, O.S.; Duarte, N.D.; Cunha, S.O.; Ascenso, J.R.; Ferreira, M.J.U.. "Triterpenoids from Euphorbia boetica". Fitoterapia 66 6 (1995): 551-552. http://www.scopus.com/inward/record.url?eid=2-s2.0-0029558311&partnerID=MN8TOARS.
  108. Ascenso, J.R.; De Azevedo, C.G.; Gonçalves, I.S.; Herdtweck, E.; Moreno, D.S.; Pessanha, M.; Romão, C.C.. "Mixed-ring and indenyl analogues of molybdenocene and tungstenocene: Preparation and characterization". Organometallics 14 8 (1995): 3901-3919. http://www.scopus.com/inward/record.url?eid=2-s2.0-0000232403&partnerID=MN8TOARS.
    10.1021/om00008a042
  109. Ferreira, M.J.U.; Ascenso, J.R.; Tavares, O.S.. "Boeticol, a new tetracyclic triterpene from Euphorbia boetica". Journal of Natural Products 58 2 (1995): 275-279. http://www.scopus.com/inward/record.url?eid=2-s2.0-0028940035&partnerID=MN8TOARS.
    10.1021/np50116a020
  110. Gigante, B.; Santos, L.; Marcelo-Curto, M.J.; Ascenso, J.. "13C and 1H NMR assignments for a series of dehydroabietic acid derivatives". Magnetic Resonance in Chemistry 33 4 (1995): 318-321. http://www.scopus.com/inward/record.url?eid=2-s2.0-84994941879&partnerID=MN8TOARS.
    10.1002/mrc.1260330416
  111. Ascenso, J.R.; De Azevedo, C.G.; Gonçalves, I.S.; Herdtweck, E.; Moreno, D.S.; Romão, C.C.; Zühlke, J.. "Stepwise synthesis of molybdenocene and mixed-ring indenyl analogues". Organometallics 13 2 (1994): 429-431. http://www.scopus.com/inward/record.url?eid=2-s2.0-0002774436&partnerID=MN8TOARS.
    10.1021/om00014a011
  112. Ascenso, J.R.; de Deus Carvalho, M.; Dias, A.R.; Romão, C.C.; Calhorda, M.J.; Veiros, L.F.. "Nuclear magnetic resonance studies of sulfur inversion in bis(cyclopentadienyl)-molybdenum and -tungsten complexes with dithioethers". Journal of Organometallic Chemistry 470 1-2 (1994): 147-152. http://www.scopus.com/inward/record.url?eid=2-s2.0-50749135366&partnerID=MN8TOARS.
  113. Ascenso, J.R.; Santos, M.A.; Fraústo Da Silva, J.J.R.; Vaz, M.C.T.A.; Drew, M.G.B.. "Protonation of diaza cyclic complexones: 1H NMR, calorimetric and molecular mechanics studies". Journal of the Chemical Society, Perkin Transactions 2 12 (1990): 2211-2218. http://www.scopus.com/inward/record.url?eid=2-s2.0-0141770428&partnerID=MN8TOARS.
    10.1039/p29900002211
  114. Amorim, M.T.S.; Ascenso, J.R.; Delgado, R.; Da Silva, J.J.R.F.. "Nuclear magnetic resonance studies of the protonation sequence of some oxaaza macrocyclic compounds". Journal of the Chemical Society, Dalton Transactions 11 (1990): 3449-3455. http://www.scopus.com/inward/record.url?eid=2-s2.0-37049075278&partnerID=MN8TOARS.
    10.1039/DT9900003449
  115. Ascenso, J.R.; de C.T. Carrondo, M.A.A.F.; Dias, A.R.; Gomes, P.T.; Fátima, M.; Piedade, M.; Romao, C.C.; Revillon, A.; Tkatchenko, I.. "Cationic benzyl nickel complexes as homogeneous catalysts for styrene oligomerization. X-ray crystal structure of [Ni(¿3-CH2C6H5)(PPh3)2]PF6 · CH2CI2". Polyhedron 8 20 (1989): 2449-2457. http://www.scopus.com/inward/record.url?eid=2-s2.0-0042953172&partnerID=MN8TOARS.
    10.1016/S0277-5387(89)80009-9
  116. Ascenso, Jose R.; Dias, Alberto R.; Gomes, Pedro T.; Romao, Carlos C.; Pham, Quang-Tho; Neibecker, Denis; Tkatchenko, Igor. "Cationic ¿3-allyl complexes: 16. Isotactic oligomerization of styrene in the presence of a homogeneous nickel(II) catalyst". Macromolecules 22 2 (1989): 998-1000. http://www.scopus.com/inward/record.url?eid=2-s2.0-0024607434&partnerID=MN8TOARS.
    10.1021/ma00192a079
  117. Ascenso, J.R.; Delgado, R.; Fraústo Da Silva, J.J.R.. "Lanthanide complexes of 1,4,7,10-tetra-azacyclotridecane-1,4,7,10-tetra-acetic acid: Proton nuclear magnetic resonance studies". Journal of the Chemical Society, Dalton Transactions 11 (1986): 2395-2398. http://www.scopus.com/inward/record.url?eid=2-s2.0-37049089590&partnerID=MN8TOARS.
    10.1039/DT9860002395
  118. Ascenso, J.R.; Harris, R.K.; Granger, P.. "High-resolution 207Pb NMR of solid organolead compounds". Journal of Organometallic Chemistry 301 2 (1986): http://www.scopus.com/inward/record.url?eid=2-s2.0-0002002370&partnerID=MN8TOARS.
    10.1016/0022-328X(86)80019-5
  119. Ascenso, J.R.; Delgado, R.; Da Silva, J.J.R.F.. "Nuclear magnetic resonance studies of the protonation sequence of cyclic tetra-azatetra-acetic acids". Journal of the Chemical Society, Perkin Transactions 2 6 (1985): 781-788. http://www.scopus.com/inward/record.url?eid=2-s2.0-37049097085&partnerID=MN8TOARS.
  120. Geraldes, C.F.G.C.; Ascenso, J.R.. "Solvent effects on the conformation of nucleotides. Part 2. Nuclear magnetic shift and relaxation effects induced by lanthanide ions on adenosine 5'-monophosphate in water-dimethyl sulphoxide". Journal of the Chemical Society, Dalton Transactions 2 (1984): 267-272. http://www.scopus.com/inward/record.url?eid=2-s2.0-37049096657&partnerID=MN8TOARS.
    10.1039/DT9840000267
  121. Ascenso, J.; Candida, M.; Vaz, T.A.; Fraústo Da Silva, J.J.R.. "NMR studies of the complexes of uramildiacetic acid". Journal of Inorganic and Nuclear Chemistry 43 6 (1981): 1255-1259. http://www.scopus.com/inward/record.url?eid=2-s2.0-0141531855&partnerID=MN8TOARS.
  122. Nunes, M.T.; Gil, V.M.S.; Ascenso, J.. "The conformation of succinic acid in aqueous solution studied by 1h and 13c nmr". Tetrahedron 37 3 (1981): 611-614. http://www.scopus.com/inward/record.url?eid=2-s2.0-0343777150&partnerID=MN8TOARS.
    10.1016/S0040-4020(01)92437-8
  123. Sherry, A.D.; Stark, C.A.; Ascenso, J.R.; Geraldes, C.F.G.C.. "Lanthanide ethylenediaminetetra-acetate chelates as aqueous shift reagents: Evidence for effective axial symmetry in bidentate cytidine 5'-monophosphate and alanine complexes". Journal of the Chemical Society, Dalton Transactions 10 (1981): 2078-2082. http://www.scopus.com/inward/record.url?eid=2-s2.0-37049097203&partnerID=MN8TOARS.
    10.1039/DT9810002078
Capítulo de livro
  1. Ascenso, J.R.. "Study of the Methanol Extracts of Euphorbia Segetalis". In PROCEEDINGS OF THE PHYTOCHEMICAL SOCIETY OF EUROPE. Kluwer Academic Publishers, 2002.
    Publicado
  2. Ascenso, J.R.. "Short Side Chain Cycloartane and other Triterpenes from Euphorbia Tuckeyana". In PROCEEDINGS OF THE PHYTOCHEMICAL SOCIETY OF EUROPE. Kluwer Academic Publishers, 2002.
    Publicado
  3. Ascenso, J.R.. "The use of Lanthanide Ions as NMR Structural Probes". In Systematics and Properties of the Lanthanides. Alemanha: Reidel, 1983.
    Publicado
Resumo em conferência
  1. Ascenso, J.R.. "Slice selective NMR analysis of lanthanum picrate distribution in extraction studies by calixarene ketone derivatives". Trabalho apresentado em SMASH, Porto, 2019.
    Publicado
  2. Ascenso, J.R.. "Efficient Binding of Halide and Pseudo-Halide Anions by Tetraphenyl(thio)urea Based Dihomooxacalix[4]arene Receptors,". Trabalho apresentado em ISMSC 2017, cambridge, 2017.
  3. Ascenso, J.R.. "Segmented polyurethanes based on the renewable isosorbide diol:an nmr study". Trabalho apresentado em 1st Joint French-Portuguese NMR Conference, Lisbon, 2016.
    Publicado
  4. Ascenso, J.R.. "Alkylammonium Cation Complexation by Conformationally Mobile Tetramethoxy of p-tert-Butyldihomooxacalix[4]arene,". Trabalho apresentado em 10th ISMSC-2015, Strasbourg, 2015.
    Publicado
  5. Ascenso, J.R.. "On the Mobility of Dialkyl Adipates by PFGSE NMR, Computer Simulations and other Property Measurement Methods". Trabalho apresentado em VI Ibero-American NMR Meeting, Alcalá Henares, 2014.
    Publicado
  6. Ascenso, J.R.. "Anion Binding Properties of Dihomooxacalix[4]arene Bidentate Urea and Thiourea Derivatives". Trabalho apresentado em 9 International Symposium on Macrocyclic and Supramolecular Chemistry, Shangai, 2013.
    Publicado
  7. Ascenso, J.R.. "Study of HSA binding to potential allergenic aldehydes by STD-NMR". Trabalho apresentado em EUROMAR 2011, Frankfurt, 2011.
    Publicado
  8. Ascenso, J.R.. "[Mo{eta5:eta2-(C5Bz4CH2Ph)}(CO)3]BAr’4: An Unusual Cationic Complex Synthesis, NMR and DFT Studies". Trabalho apresentado em 3rd EuCheMS Chemistry Congress, Nurenberg, 2010.
    Publicado
  9. Ascenso, J.R.. "Integrated metabolomics, transcriptomics and genome-wide phenotypic analyses to get insights into the global response to propionic acid stress in Saccharomyces cerevisiae". Trabalho apresentado em Yeast Genetics and Molecular Biology Conference, Manchester, 2009.

Outros

Outra produção
  1. Diffusion coefficients of perfluorinated n-alcohols in water and heavy water: experiment and computer simulation. Fluorinated surfactants find nowadays many industrial applications due to their enhanced ability to lower surface tension in aqueous solutions [1]. As a result of their extensive use, emissions of fluorinated surfactants became frequent and, because of their persistent character, have been increasingly found in the environment [2]. Both the development of theoretical models to study the environmen. 2014. Martins, Luís F. G.; Pereira, Luís A. M.; Ascenso, José R.; Morgado, Pedro; Filipe, Eduardo J. M.. http://hdl.handle.net/10174/13625.
Atividades

Orientação

Título / Tema
Papel desempenhado 		Curso (Tipo)
Instituição / Organização
2020 - Atual Probing the nano-structuring of ionic liquid based fluids using 123Xe NMR spectroscopy: towards structure-properties relationships.
Coorientador
Universidade de Lisboa Instituto Superior Técnico, Portugal
2007 - 2009 The WW domain-Smad pair
Orientador
Universidade de Lisboa Instituto Superior Técnico, Portugal
2006 - 2009 Síntese de Complexos de Titânio e Zircónio e suas Aplicações em Catálise de Hidrogenação de Cetonas
Coorientador de Sónia Cristina Namorado Gonçalves Calado
Universidade de Lisboa Instituto Superior Técnico, Portugal
1999 - 2000 Complexos Derivados de Tris-Amido-Triazamacrociclos: Síntese e Reactividade
Coorientador de Humberto dos Santos Ferreira
Universidade de Lisboa Instituto Superior Técnico, Portugal
1993 - 1994 Estudo Fitoquímico da Euphorbia boetica
Orientador
Universidade de Lisboa Instituto Superior Técnico, Portugal
1989 - 1990 Estudos de Inversão do Enxofre em Metalocenos Dobrados de Molidnénio e Tungsténio
Orientador
Universidade de Lisboa Instituto Superior Técnico, Portugal