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C. M. Nunes graduated in Chemistry from the University of Coimbra in 2004 (best student), obtained his MSc degree in Organic Chemistry in 2007 and his PhD degree in Molecular Spectroscopy in 2012. Worked as a postdoctoral researcher at the Laboratory for Molecular Cryospectroscopy and Biospectroscopy from 2013 to 2018. Besides a short postdoctoral position at the Department of Chemistry of the University of Fribourg (Switzerland), he also spent several months working as a visiting researcher at the Organometallic Chemistry Institute of the University of Oviedo (Spain), the Department of Chemistry of the University of Wisconsin-Madison (USA), and the Institute of Organic Chemistry of the Justus-Liebig University Giessen (Germany). Started his independent research career in 2019 at the Coimbra Chemistry Centre as an Auxiliary Researcher funded by the Portuguese Foundation for Science and Technology (ranked 3rt in 109 candidates). In late 2023, he was appointed Assistant Professor at the Department of Chemistry of the University of Coimbra. C. M. Nunes has published 55 papers in international peer-reviewed journals, over 50 conference proceedings, and contributed to 3 books. Highlight for 22 publications as a corresponding author and several papers in highly prestigious journals such as J. Am. Chem. Soc., Angew. Chem., and Chem. Soc. Rev. Several of his works have been selected by editorial boards, such as VIP papers in Angew. Chem. and Chem. Eur. J., a spotlight in J. Am. Chem. Soc., HOT articles in Phys. Chem. Chem. Phys., and an interview in Chemistry World. He has been invited to deliver keynote lectures at several scientific conferences and to serve as a referee in reputable journals (e.g., Nat. Commun, J. Am. Chem. Soc., Angew. Chem.). Has also served as a guest editor for two scientific journals and is currently an Associate Editor of the J. Mol. Struct. (IF = 3.84, Elsevier). He has lectured on several courses at the Department of Chemistry of the University of Coimbra. Supervised several MSc and BSc students, IAESTE international internships, and MSc-holder and Postdoc research projects. Currently, he is (co)supervising 2 Postdoc, 1 PhD and 1 MSc students. C. M. Nunes has been serving as the subdirector of the Coimbra Chemistry Centre and has been assuming management activities within the Coimbra Laser Lab research platform since 2019. He is also currently the coordinator of the Laboratory for Molecular Cryospectroscopy group. He was awarded with a grant project as PI (aCTIVE [2018-2022]: ~240 k EUR) and other as co-PI (QUANTUN [2021-2025]: ~250 k EUR), and an advanced computing project as PI (TUNCHEM [2023]: ~100 k CPU core.hours). His pioneering research program is focused on quantum tunneling chemistry, IR vibrational excitation chemistry, multidimensional tunneling computations, organic mechanisms and reactive intermediates, development of new organic reactions and organocatalysts.
Identificação

Identificação pessoal

Nome completo
CLÁUDIO MANAIA NUNES

Nomes de citação

  • Nunes, C. M.
  • C. M. Nunes

Identificadores de autor

Ciência ID
9512-4DC6-CB21
ORCID iD
0000-0002-8511-1230
Google Scholar ID
X0XKzacAAAAJ
Scopus Author Id
57211988801

Moradas

  • Department of Chemistry, University of Coimbra, Rua Larga 2, 3004-535 , Coimbra, Coimbra, Portugal (Profissional)

Websites

Domínios de atuação

  • Ciências Exatas - Química - Química Orgânica
  • Ciências Exatas - Química - Química Física

Idiomas

Idioma Conversação Leitura Escrita Compreensão Peer-review
Português (Idioma materno)
Inglês Utilizador proficiente (C2) Utilizador proficiente (C2) Utilizador proficiente (C2) Utilizador proficiente (C2) Utilizador proficiente (C2)
Espanhol; Castelhano Utilizador proficiente (C1) Utilizador proficiente (C1) Utilizador independente (B1) Utilizador proficiente (C1) Utilizador proficiente (C1)
Francês Utilizador independente (B1) Utilizador independente (B1) Utilizador elementar (A1) Utilizador independente (B1) Utilizador independente (B1)
Formação
Grau Classificação
2007/03 - 2012/04
Concluído
Chemistry (Doutoramento)
Especialização em Molecular Spectroscopy
Universidade de Coimbra Faculdade de Ciencias e Tecnologia, Portugal
"Study of Thermal and Photochemistry of Isoxazoles by Matrix-Isolation and FTIR Spectroscopy" (TESE/DISSERTAÇÃO)
Approved with distinction and honor by unanimity
2004/09 - 2007/04
Concluído
Chemistry (Mestrado)
Especialização em Organic Chemistry
Universidade de Coimbra Faculdade de Ciencias e Tecnologia, Portugal
"Pericyclic Reactions of Novel Dipolar Systems: Synthesis of Functionalized Heterocycles" (TESE/DISSERTAÇÃO)
18 / Muito bom
1999/09 - 2004/06
Concluído
Chemistry (Licenciatura)
Especialização em Industrial Chemistry
Universidade de Coimbra Faculdade de Ciencias e Tecnologia, Portugal
15 (best final mark)
Percurso profissional

Ciência

Categoria Profissional
Instituição de acolhimento
Empregador
2019/05 - 2023/08/31 Investigador Auxiliar (carreira) (Investigação) Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2020/09 - 2020/10 Investigador visitante (Investigação) Institute of Organic Chemistry, Justus-Liebig University Giessen, Germany, Alemanha
Institute of Organic Chemistry, Justus-Liebig University Giessen, Alemanha
2019/01 - 2019/04 Assistente de Investigação (carreira) (Investigação) Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019/01 - 2019/01 Investigador visitante (Investigação) IPREM, University of Pau and Pays de l'Adour, França
IPREM, University of Pau and Pays de l'Adour, França
2018/03 - 2018/04 Investigador visitante (Investigação) Institute of Organic Chemistry, Justus-Liebig University Giessen, Alemanha
Institute of Organic Chemistry, Justus-Liebig University Giessen, Alemanha
2013 - 2018 Pós-doutorado (Investigação) Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2016/07 - 2016/07 Investigador visitante (Investigação) Institute of Physics, Polish Academy of Sciences, Warsaw, Polónia
Institute of Physics, Polish Academy of Sciences, Warsaw, Polónia
2015/09 - 2015/12 Investigador visitante (Investigação) Department of Chemistry, University of Wisconsin-Madison, Estados Unidos
Department of Chemistry, University of Wisconsin-Madison, Estados Unidos
2014/06 - 2014/06 Investigador visitante (Investigação) Faculty of Chemistry, University of Wroclaw, Polónia
Faculty of Chemistry, University of Wroclaw, Polónia
2013 - 2013 Pós-doutorado (Investigação) Université de Fribourg, Suiça
Department of Chemistry, University of Fribourg, Suiça
2009/08 - 2009/11 Investigador visitante (Investigação) Institute for Physical Chemistry, University of Fribourg, Suiça
Institute for Physical Chemistry, University of Fribourg, Suiça
2008/03 - 2008/06 Investigador visitante (Investigação) Organometallic Chemistry Institute, University of Oviedo, Espanha
Organometallic Chemistry Institute, University of Oviedo, Espanha

Docência no Ensino Superior

Categoria Profissional
Instituição de acolhimento
Empregador
2023/09/01 - Atual Professor Auxiliar (Docente Universitário) Universidade de Coimbra, Portugal
Department of Chemistry, University of Coimbra, Portugal
2004/12 - 2005/06 Assistente (Docente Universitário) Universidade de Coimbra, Portugal
Department of Chemistry, University of Coimbra, Portugal

Cargos e Funções

Categoria Profissional
Instituição de acolhimento
Empregador
2024/01/04 - Atual Coordinator of the Reseach Group of the Laboratory for Molecular Cryospectroscopy Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2024/01 - Atual Subdirector de Unidade Orgânica Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019 - Atual Co-Coordinator Universidade de Coimbra, Portugal
Coimbra Laser Lab, Department of Chemistry, University of Coimbra, Portugal
2021/11 - 2023/12 Subdirector de Unidade Orgânica Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019/10 - 2021/09 Subdirector de Unidade Orgânica Universidade de Coimbra, Portugal
Coimbra Chemistry Centre, University of Coimbra, Portugal

Outros

Categoria Profissional
Instituição de acolhimento
Empregador
2023/06/15 - Atual Associate Editor of the Journal of Molecular Structure Elsevier BV, Países Baixos
Projetos

Bolsa

Designação Financiadores
2019 - 2020 Exploring Competitive Heavy-Atom Tunneling Reactions Using Experiment and Theory
Bilateral Project
Investigador
Coimbra Chemistry Centre, University of Coimbra, Portugal

Institute of Organic Chemistry, Justus-Liebig University Giessen, Alemanha
FCT (Portugal) / DAAD (Germany),
Concluído
2018 - 2019 Kinetically Unstable Compounds: Tautomerism and Photoinduced Rearrangements with Characterization at Very Low-Temperatures
Bilateral Project
Investigador
Coimbra Chemistry Centre, University of Coimbra, Portugal

Institut des Sciences Chimiques de Rennes, França

Université de Pau et des Pays de l'Adour, França
FCT (Portugal) / Programme PESSOA (France)
Concluído
2015 - 2016 Photoinduced Isomerizations in Nucleic Acid Base Analogues
Bilateral Project
Investigador
Coimbra Chemistry Centre, University of Coimbra, Portugal

Institute of Physics of Polish Academy of Sciences, Polónia
FCT (Portugal) / Ministry of Science and Higher Education (Poland)
Concluído
2013 - 2014 Photochemical Transformations of Biologically Important Molecules (Phenols and Tetrazoles) Using UV and NIR Laser Irradiation
Bilateral Project
Investigador
Coimbra Chemistry Centre, University of Coimbra, Portugal

Faculty of Chemistry, University of Wroclaw, Polónia
FCT (Portugal) / Ministry of Science and Higher Education (Poland)
Concluído

Projeto

Designação Financiadores
2022/09/01 - Atual RESETFINAS - Set-up for Modification of Rosin Resins to Promote the Compatibility of their Derivatives with Polyolefins Produced by Metallocene Catalysis
Investigador
Universidade de Coimbra, Portugal

United Resins, Portugal
PRR (Plano de Recuperação e Resiliência)
Em curso
2022/09/01 - Atual RESFINAS - Modification of Rosin Resins to Promote the Compatibility of their Derivatives with Polyolefins Produced by Metallocene Catalysis
Investigador
Universidade de Coimbra, Portugal

United Resins, Portugal
PRR (Plano de Recuperação e Resiliência)
Em curso
2022/09/01 - Atual ReMade@ARI - REcyclable MAterials DEvelopment at Analytical Research Infrastructures
Investigador
Coimbra Laser Lab, Department of Chemistry, University of Coimbra, Portugal

Helmholtz-Zentrum Dresden-Rossendorf, Alemanha
European Union
Em curso
2021/03/29 - Atual Quantum Mechanical Tunneling in Organic Chemistry: New Reactivity Paradigms and Avenues for Molecular Design
Co-Investigador Responsável (Co-IR)
Universidade de Coimbra, Portugal

Ben-Gurion University of the Negev, Israel
Fundação para a Ciência e a Tecnologia
Em curso
2023/04 - 2033/10 Multidimensional Tunneling Calculations: Exploring New Reactivity Paradigms to Drive Chemical Transformations
Investigador responsável
Universidade de Coimbra, Portugal
Rede Nacional de Computação Avançada

Fundação para a Ciência e a Tecnologia
Concluído
2018/07/26 - 2022/07/25 Chemistry Triggered by Infrared Vibrational Excitation: Developing a Powerful Tool for Highly-Selective Molecular Structure Manipulation
PTDC/QUI-QFI/28973/2017
Investigador responsável
Universidade de Coimbra, Portugal
Fundação para a Ciência e a Tecnologia

COMPETE 2020
Concluído
2016/06/01 - 2019/10/01 The Birth of High-Energy Crystals from Isolated Molecules – The Unsuspected Parenthood of Rare Conformers
Investigador
Universidade de Coimbra, Portugal

Sarspec, Lda, Portugal
Fundação para a Ciência e a Tecnologia

FEDER
Concluído
2012 - 2015 Photochemical Behavior of New Azides: Gateway to Nitrenes
Investigador
Universidade de Coimbra, Portugal

Universidade do Porto, Portugal
Fundação para a Ciência e a Tecnologia
Concluído
2012 - 2013/01/31 Optical Control of Conformationally Dependent Photochemical Reactions
Bolseiro de Pós-Doutoramento
Universidade de Coimbra, Portugal
Fundação para a Ciência e a Tecnologia

COMPETE
Concluído
2008/11/15 - 2012/01/31 Thermal reactivity and optically controlled photochemistry of three-membered ring nitrogen containing compounds, as probed by matrix-isolation infrared spectroscopy, differential scanning calorimetry and quantum chemical calculations
Investigador
Universidade de Coimbra, Portugal
Fundação para a Ciência e a Tecnologia

COMPETE
Concluído
2008/01/01 - 2010/12/31 Chiral Allenes as Tools in the Synthesis of Cyclic and Acyclic Amino Esters
Investigador
Universidade de Coimbra, Portugal
Fundação para a Ciência e a Tecnologia

COMPETE
Concluído
2005/07/15 - 2008/01/14 Pyrrolo[1,2-c]Thiazoles as Building Blocks in Organic Synthesis: Approaches to Structures with Biological Activity
Bolseiro de Mestrado
Chymiotechnon - Instituto de Ciência, Tecnologia e Inovação em Química, Portugal
Fundação para a Ciência e a Tecnologia
Concluído
Produções

Publicações

Artigo em revista
  1. Nunes, C.M.; Lopes Jesus, A.J.; Rosado, M.T.S; Fausto, R.. Autor correspondente: Nunes, C.M.. "On the Carbenic Nature of Nitrile Ylides: Experimental and Computational Characterization of Hydroxy and Amino Nitrile Ylides". European Journal of Organic Chemistry (2023): e202301103. https://doi.org/10.1002/ejoc.202301103.
    10.1002/ejoc.202301103
  2. Ferreira, G.A.; Nunes, C. M.; Lopes Jesus, A.J.; Fausto, R.. Autor correspondente: Nunes, C. M.. "The meta and para OH Substitution Effect on C-Phenyl-Nitrilimine Bond-Shift Isomers". European Journal of Organic Chemistry (2023): e202300310. https://doi.org/10.1002/ejoc.202300310.
    10.1002/ejoc.202300310
  3. Roque, J.P.L; Nunes, C.M; Schreiner, P.R.; Fausto, R. Autor correspondente: Nunes, C.M. "H-Tunneling Exhibiting Unexpectedly Small Primary Kinetic Isotope Effects". ChemRxiv (2023): https://chemrxiv.org/engage/chemrxiv/article-details/656f6721cf8b3c3cd7d9c438.
    Submetido • 10.26434/chemrxiv-2023-8h22d
  4. Nunes, C.M.; Roque, J.P.L.; Doddipatla, S.; Wood, S.A.; McMahon, R.J.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Simultaneous Tunneling Control in Conformer-Specific Reactions". Journal of the American Chemical Society 144 45 (2022): 20866-20874. https://doi.org/10.1021/jacs.2c09026.
    10.1021/jacs.2c09026
  5. Nunes, C.M.; Doddipatla, S.; Loureiro, G.F.; Roque, J.P.L.; Pereira, N.A.M.; Pinho e Melo, T.M.V.D.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Differential Tunneling-Driven and Vibrationally-Induced Reactivity in Isomeric Benzazirines". Chemistry - A European Journal (#VIP Paper) 28 67 (2022): e202202306. https://doi.org/10.1002/chem.202202306.
    10.1002/chem.202202306
  6. Lopes Jesus, A.J.; Nunes, C.M.; Reva, I.. "Conformational Structure, Infrared Spectra and Light-Induced Transformations of Thymol Isolated in Noble Gas Cryomatrices". Photochem 2 2 (2022): 405-422. http://dx.doi.org/10.3390/photochem2020028.
    10.3390/photochem2020028
  7. Nunes, C.M.; Pereira, N.A.M.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Photochromism of a Spiropyran in Low-Temperature Matrices: Unprecedented Bidirectional Switching between a Merocyanine and an Allene Intermediate". The Journal of Physical Chemistry A 126 14 (2022): 2222-2233. https://doi.org/10.1021/acs.jpca.2c01105.
    10.1021/acs.jpca.2c01105
  8. Fausto, R.; Ildiz, G.O.; Nunes, C.M.. "IR-induced and tunneling reactions in cryogenic matrices: the (incomplete) story of a successful endeavor". Chemical Society Reviews 51 7 (2022): 2853-2872. https://doi.org/10.1039/D1CS01026C.
    10.1039/D1CS01026C
  9. Doddipatla, S.; Ferreira, G.I.; Sidir, Y.G.; Nunes, C.M.; Fausto, R.. "Breaking and Formation of Intramolecular Hydrogen Bonds in Dihydroxybenzaldehydes through UV-Induced Conformational Changes in a Low-Temperature Matrix". Journal of Physical Chemistry A 126 46 (2022): 8645-8657. https://doi.org/10.1021/acs.jpca.2c05839.
  10. Viegas, L.P.; Nunes, C.M.; Fausto, R.. "Spin-forbidden heavy-atom tunneling in the ring-closure of triplet cyclopentane-1,3-diyl". Physical Chemistry Chemical Physics (#PCCP HOT Article) 23 (2021): 5797-5803. https://doi.org/10.1039/D1CP00076D.
    10.1039/D1CP00076D
  11. Nunes, C.M.; Pereira, N.A.M.; Viegas, L.P.; Pinho E Melo, T.M.V.D.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Inducing molecular reactions by selective vibrational excitation of a remote antenna with near-infrared light". Chemical Communications 57 75 (2021): 9570-9573. http://dx.doi.org/10.1039/d1cc03574f.
    10.1039/d1cc03574f
  12. Reva, I.; Jesus, A.J.L.; Nunes, C.M.; Roque, J.P.L.; Fausto, R.. "UV-Induced Photochemistry of 1,3-Benzoxazole, 2-Isocyanophenol, and 2-Cyanophenol Isolated in Low-Temperature Ar Matrixes". Journal of Organic Chemistry 86 9 (2021): 6126-6137. https://doi.org/10.1021/acs.joc.0c02970.
    10.1021/acs.joc.0c02970
  13. Roque, J.P.L.; Nunes, C.M.; Viegas, L.P.; Pereira, N.A.M.; Pinho E Melo, T.M.V.D.; Schreiner, P.R.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Switching on H-Tunneling through Conformational Control". Journal of the American Chemical Society (#JACS Spotlight) 143 22 (2021): 8266-8271. https://doi.org/10.1021/jacs.1c04329.
    10.1021/jacs.1c04329
  14. Pereira, N.A.M.; Nunes, C.M.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Evidence of IR-Induced Chemistry in a Neat Solid: Tautomerization of Thiotropolone by Thermal, Electronic, and Vibrational Excitations". Journal of Physical Chemistry A 125 29 (2021): 6394-6403. https://doi.org/10.1021/acs.jpca.1c04081.
    10.1021/acs.jpca.1c04081
  15. Nunes, C.M.; Pereira, N.A.M.; Reva, I.; Amado, P.S.M.; Cristiano, M.L.S.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Bond-Breaking/Bond-Forming Reactions by Vibrational Excitation: Infrared-Induced Bidirectional Tautomerization of Matrix-Isolated Thiotropolone". The Journal of Physical Chemistry Letters 11 19 (2020): 8034-8039. https://doi.org/10.1021/acs.jpclett.0c02272.
    10.1021/acs.jpclett.0c02272
  16. Nunes, C.M.; Viegas, L.P.; Wood, S.A.; Roque, J.P.L.; McMahon, R.J.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Heavy-Atom Tunneling Through Crossing Potential Energy Surfaces: Cyclization of a Triplet 2-Formylarylnitrene to a Singlet 2,1-Benzisoxazole". Angewandte Chemie International Edition (#VIP Paper) 59 40 (2020): 17622-17627. https://doi.org/10.1002/anie.202006640.
    10.1002/anie.202006640
  17. Lopes Jesus, A.J.; Reva, I.; Nunes, C.M.; Roque, J.P.L.; Pinto, S.M.V.; Fausto, R.. "Kinetically unstable 2-isocyanophenol isolated in cryogenic matrices: Vibrational excitation, conformational changes and spontaneous tunneling". Chemical Physics Letters 747 (2020): 137069. http://dx.doi.org/10.1016/j.cplett.2019.137069.
    10.1016/j.cplett.2019.137069
  18. Nunes, C.M.; Eckhardt, A.K. ; Reva, I.; Fausto, R.; Schreiner, P.R.. Autor correspondente: Nunes, C.M.. "Competitive Nitrogen versus Carbon Tunneling". Journal of the American Chemical Society 141 36 (2019): 14340-14348. https://doi.org/10.1021/jacs.9b06869.
    10.1021/jacs.9b06869
  19. Lopes Jesus, A.J.; Nunes, C.M.; Reva, I.; Pinto, S.M.V.; Fausto R.. "Effects of Entangled IR Radiation and Tunneling on the Conformational Interconversion of 2-Cyanophenol". The Journal of Physical Chemistry A 123, 20 (2019): 4396-4405. https://doi.org/10.1021/acs.jpca.9b01382.
    10.1021/acs.jpca.9b01382
  20. Góbi, S.; Nunes, C.M.; Reva, I.; Tarczay, G.; Fausto, R.. "S–H rotamerization via tunneling in a thiol form of thioacetamide". Physical Chemistry Chemical Physics 21 31 (2019): 17063-17071. https://doi.org/10.1039/C9CP03417J.
    10.1039/C9CP03417J
  21. Góbi, S.; Reva, I.; Csonka, I.P.; Nunes, C.M.; Tarczay, G.; Fausto, R.. "Selective conformational control by excitation of NH imino vibrational antennas". Physical Chemistry Chemical Physics (#PCCP HOT Article) 21 45 (2019): 24935-24949. https://doi.org/10.1039/C9CP05370K.
    10.1039/c9cp05370k
  22. Nunes, C.M.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Conformational isomerizations triggered by vibrational excitation of second stretching overtones". Physical Chemistry Chemical Physics (#PCCP HOT Article) 21 45 (2019): 24993-25001. https://doi.org/10.1039/C9CP05070A.
    10.1039/c9cp05070a
  23. Lopes Jesus, A.J.; Nunes, C.M.; Fausto, R.; Reva, I.. "Conformational control over an aldehyde fragment by selective vibrational excitation of interchangeable remote antennas". Chemical Communications 54 38 (2018): 4778-4781. https://doi.org/10.1039/C8CC01052H.
    10.1039/C8CC01052H
  24. Nunes, C.M.; Gudmundsdottir, A.D.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Preface “Structure, Spectroscopy and Chemistry of Reactive Intermediates”". Journal of Molecular Structure 1172 (2018): 1-2. https://doi.org/10.1016/j.molstruc.2018.06.027.
    10.1016/j.molstruc.2018.06.027
  25. Nunes, C.M.; Pinto, S.M.V.; Reva, I.; Rosado, M.T.S.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Photochemistry of matrix-isolated 3-chloro-1,2-benzisoxazole: Generation and characterization of 2-cyanophenoxyl radical and other reactive intermediates". Journal of Molecular Structure 1172 (2018): 34-41. https://doi.org/10.1016/j.molstruc.2017.11.009.
    10.1016/j.molstruc.2017.11.009
  26. Nunes, C.M.; Reva, I.; Kozuch, S.; McMahon, R.J.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Photochemistry of 2-Formylphenylnitrene: A Doorway to Heavy-Atom Tunneling of a Benzazirine to a Cyclic Ketenimine". Journal of the American Chemical Society 139 48 (2017): 17649-17659. https://doi.org/10.1021/jacs.7b10495.
    10.1021/jacs.7b10495
  27. Soares, M.I.L.; Nunes, C.M.; Gomes, C.S.B.; Pinho E Melo, T.M.V.D.; Fausto, R.. "Conformational behaviour, photochemistry and flash vacuum pyrolysis of a 2-(1H-tetrazol-1-yl)thiophene". New Journal of Chemistry 41 24 (2017): 15581-15589. https://doi.org/10.1039/C7NJ02775C.
    10.1039/c7nj02775c
  28. Nunes, C.M.; Pinto, S.M.V.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "On the Photochemistry of 1,2-Benzisoxazole: Capture of Elusive Spiro-2H-azirine and Ketenimine Intermediates". European Journal of Organic Chemistry 2016 24 (2016): 4152-4158. https://doi.org/10.1002/ejoc.201600668.
    10.1002/ejoc.201600668
  29. Nunes, C.M.; Pinto, S.M.V.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Photochemistry of 3-amino-1,2-benzisoxazole: unexpected photoisomerization of an amino-spiro-2H-azirine to a 1H-diazirine". Tetrahedron Letters 57 46 (2016): 5038-5041. https://doi.org/10.1016/j.tetlet.2016.09.098S.
    10.1016/j.tetlet.2016.09.098
  30. Nunes, C.M.; Knezz, S.N.; Reva, I.; Fausto, R.; McMahon, R.J.. "Evidence of a Nitrene Tunneling Reaction: Spontaneous Rearrangement of 2-Formyl Phenylnitrene to an Imino Ketene in Low-Temperature Matrixes". Journal of the American Chemical Society 138 47 (2016): 15287-15290. https://doi.org/10.1021/jacs.6b07368.
    10.1021/jacs.6b07368
  31. Nunes, C.M.; Reva, I.; Fausto, R.; Bégué, D.; Wentrup, C.. "Bond-shift isomers: The co-existence of allenic and propargylic phenylnitrile imines". Chemical Communications 51 79 (2015): 14712-14715. https://doi.org/10.1039/C5CC03518J.
    10.1039/c5cc03518j
  32. Reva, I.; Nunes, C.M.; Biczysko, M.; Fausto, R.. "Conformational switching in pyruvic acid isolated in Ar and N2 matrixes: Spectroscopic analysis, anharmonic simulation, and tunneling". Journal of Physical Chemistry A 119 11 (2015): 2614-2627. https://doi.org/10.1021/jp509578c.
    10.1021/jp509578c
  33. Nunes, C.M.; Reva, I.; Rosado, M.T.S.; Fausto, R.. Autor correspondente: Nunes, C.M.. "The Quest for Carbenic Nitrile Imines: Experimental and Computational Characterization of C-Amino Nitrile Imine". European Journal of Organic Chemistry 2015 34 (2015): 7484-7493. https://doi.org/10.1002/ejoc.201501153.
    10.1002/ejoc.201501153
  34. Silva, P.A.; Maria, T.M.R.; Nunes, C.M.; Eusébio, M.E.S.; Fausto, R.. "Intermolecularly-induced conformational disorder in ferrocene, 1-bromoferrocene and 1,1'-dibromoferrocene". Journal of Molecular Structure 1078 (2014): 90-105. https://doi.org/10.1016/j.molstruc.2013.12.031.
    10.1016/j.molstruc.2013.12.031
  35. Wentrup, C.; Nunes, C.M.; Reva, I.. "Comment on "computational Study on the Vinyl Azide Decomposition"". Journal of Physical Chemistry A 118 27 (2014): 5122-5123. https://doi.org/10.1021/jp503958z.
    10.1021/jp503958z
  36. Nunes, C.M.; Araujo-Andrade, C.; Fausto, R.; Reva, I.. Autor correspondente: Nunes, C.M.. "Generation and characterization of a 4p-electron three-membered ring 1H-diazirine: An elusive intermediate in nitrile imine-carbodiimide isomerization". Journal of Organic Chemistry 79 8 (2014): 3641-3646. https://doi.org/10.1021/jo402744f.
    10.1021/jo402744f
  37. Krupa, J.; Wierzejewska, M.; Nunes, C.M.; Fausto, R.. "UV-tunable laser induced phototransformations of matrix isolated anethole". Journal of Chemical Physics 140 105102 (2014): https://doi.org/10.1063/1.4867896.
    10.1063/1.4867896
  38. Soares, M.I.L.; Nunes, C.M.; Gomes, C.S.B.; Pinho E Melo, T.M.V.D.. "Thiazolo[3,4-b]indazole-2,2-dioxides as masked extended dipoles: Pericyclic reactions of benzodiazafulvenium methides". Journal of Organic Chemistry 78 2 (2013): 628-637. https://doi.org/10.1021/jo302463q.
    10.1021/jo302463q
  39. Nunes, C.M.; Lapinski, L.; Fausto, R.; Reva, I.. "Near-IR laser generation of a high-energy conformer of L-alanine and the mechanism of its decay in a low-temperature nitrogen matrix". Journal of Chemical Physics 138 125101 (2013): https://doi.org/10.1063/1.4795823.
    10.1063/1.4795823
  40. Ildiz, G.O.; Nunes, C.M.; Fausto, R.. "Matrix isolation infrared spectra and photochemistry of hydantoin". Journal of Physical Chemistry A 117 4 (2013): 726-734. https://doi.org/10.1021/jp3107233.
    10.1021/jp3107233
  41. Nunes, C.M.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Capture of an elusive nitrile ylide as an intermediate in isoxazole-oxazole photoisomerization". Journal of Organic Chemistry 78 21 (2013): 10657-10665. https://doi.org/10.1021/jo4015672.
    10.1021/jo4015672
  42. Nunes, C.M.; Reva, I.; Pinho E Melo, T.M.V.D.; Fausto, R.. Autor correspondente: Nunes, C.M.. "UV-laser photochemistry of isoxazole isolated in a low-temperature matrix". Journal of Organic Chemistry 77 19 (2012): 8723-8732. https://doi.org/10.1021/jo301699z.
    10.1021/jo301699z
  43. Ildiz, G.O.; Nunes, C.M.; Kus, N.; Fausto, R.. "FTIR investigation of the O-H...Xe interaction in simple carboxylic acids in solid xenon". Journal of Chemical Physics 137 064309 (2012): https://doi.org/10.1063/1.4740243.
    10.1063/1.4740243
  44. Nunes, C.M.; Reva, I.; Pinho E Melo, T.M.V.D.; Fausto, R.; Šolomek, T.; Bally, T.. "The pyrolysis of isoxazole revisited: A new primary product and the pivotal role of the vinylnitrene. A low-temperature matrix isolation and computational study". Journal of the American Chemical Society 133 46 (2011): 18911-18923. https://doi.org/10.1021/ja207717k.
    10.1021/ja207717k
  45. Lopes, S.; Nunes, C.M.; Gómez-Zavaglia, A.; Pinho E Melo, T.M.V.D.; Fausto, R.. "Structure and photochemical behaviour of 3-azido-acrylophenones: A matrix isolation infrared spectroscopy study". Tetrahedron 67 40 (2011): 7794-7804. https://doi.org/10.1016/j.tet.2011.07.084.
    10.1016/j.tet.2011.07.084
  46. Lopes, S.; Nunes, C.M.; Gómez-Zavaglia, A.; Pinho E Melo, T.M.V.D.; Fausto, R.. "Photochemistry and vibrational spectra of matrix-isolated methyl 4-chloro-5-phenylisoxazole-3-carboxylate". Journal of Physical Chemistry A 115 7 (2011): 1199-1209. https://doi.org/10.1021/jp110705c.
    10.1021/jp110705c
  47. Nunes, C.M.; Ramos Silva, M.; Matos Beja, A.; Fausto, R.; Pinho e Melo, T.M.V.D.. "Cycloaddition of trifluoromethyl azafulvenium methides: synthesis of new trifluoromethylpyrrole-annulated derivatives". Tetrahedron Letters 51 2 (2010): 411-414. https://doi.org/10.1016/j.tetlet.2009.11.033.
    10.1016/j.tetlet.2009.11.033
  48. Lopes, S.; Nunes, C.M.; Gómez-Zavaglia, A.; Pinho E Melo, T.M.V.D.; Fausto, R.. "Conformational space and vibrational spectra of methyl 4-chloro-5-phenyl-1, 3-oxazole-2-carboxylate". Journal of Physical Chemistry A 114 34 (2010): 9074-9082. https://doi.org/10.1021/jp103665b.
    10.1021/jp103665b
  49. Lopes, S.M.M.; Nunes, C.M.; Pinho E Melo, T.M.V.D.. "4-Isoxazolines and pyrroles from allenoates". Tetrahedron 66 32 (2010): 6078-6084. https://doi.org/10.1016/j.tet.2010.06.010.
    10.1016/j.tet.2010.06.010
  50. Nunes, C.M.; Lopes, S.; Pinho e Melo, T.M.V.D.; Fausto, R.. "Spectroscopic and theoretical investigation of the conformational space of a pyrazolo-thiazole precursor of extended dipole diazafulvenium methide intermediates". Journal of Molecular Structure 921 1-3 (2009): 101-108. https://doi.org/10.1016/j.molstruc.2008.12.061.
    10.1016/j.molstruc.2008.12.061
  51. Fonseca, S.M.; Burrows, H.D.; Nunes, C.M.; Pinho e Melo, T.M.V.D.. "On the photophysical behaviour of 4-halo-5-phenyl-oxazoles and isoxazoles: A correction and observations on the photoinduced isomerisation and degradation of methyl 4-halo-5-phenyl-isoxazole-3-carboxylates". Chemical Physics Letters 474 1-3 (2009): 84-87. https://doi.org/10.1016/j.cplett.2009.04.028.
    10.1016/j.cplett.2009.04.028
  52. Lopes, S.; Nunes, C.M.; Fausto, R.; Pinho e Melo, T.M.V.D.. "4-Halo-1,3-oxazoles: Unambiguous structural assignment of 2-halo-2-benzoyl-2H-azirine-3-carboxylates thermal ring expansion products". Journal of Molecular Structure 919 1-3 (2009): 47-53. https://doi.org/10.1016/j.molstruc.2008.08.014.
    10.1016/j.molstruc.2008.08.014
  53. Pinho E Melo, T.M.V.D.; Nunes, C.M.; Soares, M.I.L.; Paixão, J.A.; Beja, A.M.; Silva, M.R.. "Chemistry of diazafulvenium methides in the synthesis of functionalized pyrazoles". Journal of Organic Chemistry 72 12 (2007): 4406-4415. https://doi.org/10.1021/jo070265x.
    10.1021/jo070265x
  54. Pinho e Melo, T.M.V.D.; Soares, M.I.L.; Nunes, C.M.. "'Higher-order' azomethine ylides in the synthesis of functionalized pyrroles and 5-oxo-5H-pyrrolizines". Tetrahedron 63 8 (2007): 1833-1841. https://doi.org/10.1016/j.tet.2006.12.025.
    10.1016/j.tet.2006.12.025
  55. Gomes, P.J.S.; Nunes, C.M.; Pais, A.A.C.C.; Pinho e Melo, T.M.V.D.; Arnaut, L.G.. "1,3-Dipolar cycloaddition of azomethine ylides generated from aziridines in supercritical carbon dioxide". Tetrahedron Letters 47 31 (2006): 5475-5479. https://doi.org/10.1016/j.tetlet.2006.05.179.
    10.1016/j.tetlet.2006.05.179
  56. Fonseca, S.M.; Burrows, H.D.; Nunes, C.M.; Pinho e Melo, T.M.V.D.; Gonsalves, A.M.D'A.. "On the photophysical behaviour of 4-halo-5-phenylisoxazoles". Chemical Physics Letters 414 1-3 (2005): 98-101. https://doi.org/10.1016/j.cplett.2005.08.056.
    10.1016/j.cplett.2005.08.056
Artigo em revista (magazine)
  1. Alves, A.J.S. ; Macedo, J.; Alves, C.; Brito, A.L.B.; Justino, L.L.G.; Nunes, C.M.; Jesus, A.J.L.; et al. "Modification of Rosin Properties: Contribuition of Organic and Computational Chemistry", Resinae, 2023, https://rn21.forestwise.pt/wp-content/uploads/2023/12/Resinae-EN.pdf.
Capítulo de livro
  1. Roque, J.P.L.; Nunes, C.M.; Fausto, R.. "Matrix Isolation in Heterocyclic Chemistry". In Heterocycles - Synthesis, Catalysis, Sustainability and Characterization, editado por Pinho e Melo, T.M.V.D.; Pinheiro, M., 401-451. Weinheim: Wiley-VCH, 2022.
    10.1002/9783527832002.ch12
  2. Nunes, C.M.; Reva, I.; Fausto, R.. Autor correspondente: Nunes, C.M.. "Direct Observation of Tunnelling Reactions by Matrix Isolation Spectroscopy". In Tunnelling in Molecules: Nuclear Quantum Effects from Bio to Physical Chemistry, editado por Kästner, J.; Kozuch, S., 1-60. Cambridge: Royal Society of Chemistry, 2021.
    10.1039/9781839160370-00001
Edição de número de revista
  1. Reva, I.; Nunes, C.M.; Lopes Jesus, A.J.. "Special Issue: Photochemical Reactions at Low Temperature". Molecules (2020): https://www.mdpi.com/si/21648.
    Editor convidado
  2. Nunes, C.M.; Gudmundsdottir, A.D.; Fausto, R.. "Special Issue: Structure, Spectroscopy and Chemistry of Reactive Intermediates". Journal of Molecular Structure 1172 (2018): https://www.sciencedirect.com/journal/journal-of-molecular-structure/vol/1172.
    Editor convidado
Poster em conferência
  1. José P. L. Roque; Nunes, C. M.; Luís P. Viegas; Srinivas Doddipatla; Samuel A. Wood; Robert J. McMahon; Rui Fausto. "Simultaneous Tunneling Control in Conformer Specific Reactions". Trabalho apresentado em 1st Thematic School on Electronic and Vibrational Spectroscopies Applied to Reaction Mechanisms, 2023.
  2. José P. L. Roque; Nunes, C. M.; Luís P. Viegas; Srinivas Doddipatla; Samuel A. Wood; Robert J. McMahon; Rui Fausto. "Simultaneous Tunneling Control in Conformer Specific Reactions". Trabalho apresentado em 28th National Meeting of the Portuguese Chemical Society, 2023.
  3. Nelson A. M. Pereira; Nunes, C. M. ; Igor Reva; Rui Fausto. "Tautomerization of Thiotropolone Explored Under Different Conditions: Cryogenic Noble Gas Matrices and Neat Solid State". Trabalho apresentado em 3rd Chemistry Center Day, 2021.
  4. Nunes, C. M. ; José P. L. Roque; Srinivas Doddipatla; Samuel A. Wood; Robert J. McMahon; Rui Fausto. "Simultaneous Tunneling Control in Conformer Specific Reactions". Trabalho apresentado em 3rd Chemistry Center Day, 2021.
  5. José P. L. Roque; Nunes, C. M. ; Luís P. Viegas; Nelson A. M. Pereira; Teresa M. D. V. Pinho e Melo; Rui Fausto. "H-Tunneling Activated by Vibrational Excitation". Trabalho apresentado em 14th National Physical Chemistry Meeting, 2021.
  6. Igor Reva; Nunes, C. M. ; Rui Fausto; A. J. Lopes Jesus. "Control of Molecular Conformation with Near-Infrared Laser Light". Trabalho apresentado em 26th National Meeting of the Portuguese Chemical Society, 2019.
  7. Sándor Góbi; Nunes, C. M. ; Igor Reva; Rui Fausto. "Chemistry Triggered by Infrared Vibrational Excitation - A Case Study of Thiourea". Trabalho apresentado em 34th European Congress on Molecular Spectroscopy, 2018.
  8. A. J. Lopes Jesus; Nunes, C. M. ; Igor Reva; Rui Fausto. "Conformational Control of an Aldehyde Fragment by Selective Vibrational Excitation of Interchangeable Remote Antennas". Trabalho apresentado em 34th European Congress on Molecular Spectroscopy, 2018.
  9. Nunes, C. M. ; Igor Reva; Rui Fausto; Sam A. Wood; Robert J. McMahon. Autor correspondente: Nunes, C. M.. "Cyclization of Triplet 2-Formyl-Phenylnitrene to 2,1-Benzisoxazole: A New Heavy-atom Tunneling Event?". Trabalho apresentado em 24th IUPAC Conference on Physical Organic Chemistry, 2018.
  10. Nunes, C. M. ; Igor Reva; Rui Fausto; André, K. Eckhardt; Peter R. Schreiner. Autor correspondente: Nunes, C. M.. "Competitive Nitrogen vs Carbon Tunneling in a Benzazirine". Trabalho apresentado em International Symposium on Reactive Intermediates and Unusual Molecules, 2018.
  11. Sandra M. V. Pinto; Nunes, C. M. ; Igor Reva; Rui Fausto,. "On the Photochemistry of 3-Amino-1,2-Benzisoxazole: The Unexpected Photoisomerization of an Amino-Spiro-2H-Azirine to a 1H-Diazirine". Trabalho apresentado em 28th International Conference on Photochemistry, 2017.
  12. Nunes, C. M. ; Igor Reva; Sebastian Kozuch; Robert J. McMahon; Rui Fausto. Autor correspondente: Nunes, C. M.. "Photochemistry of Triplet 2-Formyl-Phenylnitrene in Low-Temperature Matrix: Heavy-Atom Tunneling of Benzazirine into Cyclic Ketenimine". Trabalho apresentado em International Symposium on Reactive Intermediates and Unusual Molecules, 2017.
  13. Sandra M. V. Pinto; Nunes, C. M. ; Igor Reva; Rui Fausto. "Generation of a Higher-Energy Conformer of 2-Cyanophenol Isolated in Low-Temperature Matrices". Trabalho apresentado em 5th Portuguese Young Chemists Meeting, 2016.
  14. Sandra M. V. Pinto; Nunes, C. M. ; Igor Reva; Rui Fausto. "Photochemistry of 1,2-Benzisoxazoles in Low-Temperature Matrices". Trabalho apresentado em MOLecules In Motion, From Potentials to Dynamics: The Starting Journey (COST Action), 2016.
  15. Rui Fausto; M. E. S. Eusébio; T. M. R. Maria; Patrícia A. Silva; Nunes, C. M.. "Noteworthy High-Energy-Conformation Selection in Crystalline 1-Bromoferrocene and 1,1’-Dibromoferrocene". Trabalho apresentado em JEEP 2015, 41st Conference on Phase Equilibria, 2015.
  16. Sandra M. V. Pinto; Nunes, C. M. ; Igor Reva; Rui Fausto. "Capture of an Elusive Spiro-2H-Azirine and Ketenimine: Key Intermediates in the Photochemistry of 1,2-Benzisoxazole". Trabalho apresentado em 4th Portuguese Young Chemists Meeting, 2014.
  17. Gulce O. Ildiz; Nunes, C. M. ; Rui Fausto. "Matrix Isolation Infrared Spectra and Photochemistry of Hydantoin". Trabalho apresentado em 1st International Turkish Congress on Molecular Spectroscopy, 2013.
  18. Gulce O. Ildiz; Nunes, C. M. ; Nihal Kus; Rui Fausto. "FTIR Investigation of the O-H...Xe Interaction in Simple Carboxylic Acids In Solid Xenon". Trabalho apresentado em 31st European Congress on Molecular Spectroscopy, 2012.
  19. Nunes, C. M. ; Igor Reva; Teresa M. V. D. Pinho e Melo; Rui Fausto. Autor correspondente: Nunes, C. M.. "UV Laser Photochemistry of Isoxazole Isolated in Low-Temperature Matrix". Trabalho apresentado em 24th IUPAC Symposium on Photochemistry, 2012.
  20. Nunes, C. M. ; Igor Reva; Rui Fausto; Teresa M. V. D. Pinho e Melo. Autor correspondente: Nunes, C. M.. "Pulsed Pyrolysis of Isoxazole. A Low-Temperature Matrix Isolation Infrared Spectroscopy Study". Trabalho apresentado em 30th European Congress on Molecular Spectroscopy, 2010.
  21. Susy Lopes; Igor Reva; Nunes, C. M. ; Teresa M. V. D. Pinho e Melo; Rui Fausto. "Photochemical Study of Methyl Aziridine-2-Carboxylate Isolated in Low-Temperature Inert Matrices: Combined Computational and Spectroscopic (FTIR) Study". Trabalho apresentado em 42nd IUPAC Congress: Chemistry Solution, 2009.
  22. Nunes, C. M. ; Igor Reva; Susy Lopes; Teresa M. V. D. Pinho e Melo; Rui Fausto. Autor correspondente: Nunes, C. M.. "Photochemistry of 3,5-Dimethylisoxazole in Low-Temperature Inert Matrices: Combined Computational and Spectroscopic (FTIR) Study". Trabalho apresentado em 42nd IUPAC Congress: Chemistry Solution, 2009.
  23. Nunes, C. M. ; Rui Fausto; Teresa M. V. D. Pinho e Melo. "1,3-Dipolar Cycloaddition of Trifluoromethyl Azafulvenium Methides Generated Under Microwave Irradiation. A New Reactivity Model". Trabalho apresentado em 21st International Symposium: Synthesis in Organic Chemistry, 2009.
  24. Nunes, C. M. ; Teresa M. V. D. Pinho e Melo; Rui Fausto; Ana M. Beja; Manuela R. Silva. Autor correspondente: Nunes, C. M.. "Synthesis of New Chiral 7-Trifluoromethyl-1H,3H-Pyrrolo[1,2-c]Thiazoles". Trabalho apresentado em 8th National Organic Chemistry Meeting, 2009.
  25. Nunes, C. M. ; Susy Lopes; Teresa M. V. D. Pinho e Melo; Rui Fausto. Autor correspondente: Nunes, C. M.. "Matrix Isolation FTIR Spectroscopic and Theoretical Study of Dimethyl 2,2-Dioxo-1H,3H-Pyrazolo[1,5-c][1,3]Thiazole-6,7-Dicarboxylate". Trabalho apresentado em 29th European Congress on Molecular Spectroscopy, 2008.
  26. Lopes, Susy; Andreia Gómez-Zavaglia; Nunes, C. M. ; Teresa M. V. D. Pinho e Melo; Rui Fausto. "Photochemistry and Vibrational Spectra of Isolated Methyl (2Z)-2-Azido-3-Chloro-4-Oxo-4-Phenylbut-2-Enoate". Trabalho apresentado em 41st IUPAC World Chemistry Congress, 2007.
  27. Maria I. L. Soares; Susana M. M. Lopes; Nunes, C. M. ; Teresa M. V. D. Pinho e Melo. "The Rearrangement of C-Vinylpyrroles to C-Allylpyrroles". Trabalho apresentado em 7th National Organic Chemistry Meeting and 1st Luso-French Symposium, 2007.
  28. Lopes, Susy; Andreia Gómez-Zavaglia; Nunes, C. M. ; Teresa M. V. D. Pinho e Melo; Rui Fausto. "Matrix Isolation Low Temperature Solid State FTIR Spectroscopy Study of Methyl 4-Chloro-5-Phenylisoxazole-3-Carboxylate". Trabalho apresentado em 8th National Physical Chemistry Meeting, 2007.
  29. Nunes, C. M. ; Maria I. L. Soares; Teresa M.V.D. Pinho e Melo. "Thermolysis of 1-Methyl-Pyrrolo[1,2-c]Tiazoles-2,2-Dioxides: Synthesis and Reactivity of C-Vinylpyrroles". Trabalho apresentado em 4th Spanish, Portuguese, Japanese Symposium on Organic Chemistry, 2006.
  30. Paulo J. S. Gomes; Nunes, C. M. ; Teresa M. V. D. Pinho e Melo; Luis G. Arnaut. "1,3-Dipolar Cycloadditions of Aziridines. The Use of Electron Transfer as an Example of Photocatalysis". Trabalho apresentado em ACENET (ERA -NET) Integrated Course on Catalysis, 2006.
  31. Paulo J. S. Gomes; Nunes, C. M. ; Alberto C. C. Pais; Teresa M. V. D. Pinho e Melo; Arnaut, Luis G.. Autor correspondente: Nunes, C. M.. "1,3-Dipolar Cycloadditions of Azomethine Ylides in Supercritical Carbon Dioxide". Trabalho apresentado em 4th Transmediterranean Colloquium on Heterocyclic Chemistry, 2006.
  32. Teresa M. V. D. Pinho e Melo; Clara S .B. Gomes; Patrícia O. Flórido; Nunes, C. M. ; António M. d’A. R. Gonsalves. "Synthesis and Reactivity of 4-Haloisoxazoles". Trabalho apresentado em 19th National Meeting of the Portuguese Chemical Society, 2004.
Tese / Dissertação
  1. Cláudio M. Nunes. "Study of Thermal and Photochemistry of Isoxazoles by Matrix-Isolation and FTIR Spectroscopy". Doutoramento, Department of Chemistry, University of Coimbra, 2012.
  2. Cláudio M. Nunes. "Pericyclic Reactions of Novel Dipolar Systems: Synthesis of Functionalized Heterocycles". Mestrado, Department of Chemistry, University of Coimbra, 2006.
Tradução
  1. Edited by Rocha-Filho, R.C.; Fausto, R.. Grandezas, Unidades e Símbolos em Físico-Química (Symbols in Physical Chemistry, IUPAC Green Book, 3rd Edition). Publicações SBQ. 2018.
Website
  1. Nunes, C.M.. Research group webpage. 2019. https://sites.google.com/view/cmnunes.

Outros

Outra produção
  1. "Inside Back Cover". Chemical Communications 54 38 (2018): 4883-4883. 2018. Lopes Jesus, A.J.; Nunes, C.M.; Fausto, R.; Reva, I.. http://dx.doi.org/10.1039/c8cc90209g..
    10.1039/c8cc90209g
  2. "Back Cover". Chemical Communications 51 79 (2015): 14814-14814. 2015. Nunes, C.M.; Reva, I.; Fausto, R.; Bégué, D.; Wentrup, C.. https://doi.org/10.1039/C5CC90426A.
    10.1039/C5CC90426A
Atividades

Apresentação oral de trabalho

Título da apresentação Nome do evento
Anfitrião (Local do evento)
2023/09/18 Quantum Tunneling Reactions: Discoveries on the Slippery PES of Arylnitrenes (Invited Plenary Lecture/Presenting Author) Solvation Chemistry and Reactive Molecules (WE-Heraeus-Seminar)
(Bad Honnef, Alemanha)
2023/09/06 Exploring Quantum Tunneling in Organic Reactions 17th Iberian Joint Meeting on Atomic and Molecular Physics
(Coimbra, Portugal)
2023/07/24 Manipulation of Organic Molecules by Infrared Vibrational Excitation (Invited Keynote Lecture/Presenting Author) 28th National Meeting of the Portuguese Chemical Society
(Aveiro, Portugal)
2022/09/12 IR-Induced and Tunneling-Driven Reactions in Cryomatrices (Invited Plenary Lecture/Presenting Author) 16th International Conference on Molecular Spectroscopy
(Szczawnica, Polónia)
2022/07/08 Unprecedented Quantum Tunneling Reaction from the Chemistry of 2-Formylphenylnitrenes 5th Chemistry and Physics at Low Temperatures
(Visegrád, Hungria)
2022/07/06 Chemistry Triggered by Infrared Vibrational Excitation in Cryogenic Matrices (Invited Keynote Lecture/Presenting Author) 5th Chemistry and Physics at Low Temperatures
(Visegrád, Hungria)
2022/04/22 Manipulation of Organic Molecules by Vibrational Excitation with Near Infrared Light (Presenting Author) 14th National Organic Chemistry Meeting and 7th National Medicinal Chemistry Meeting
(Costa da Caparica, Portugal)
2021/12/15 Activation of H-Tunneling by Vibrational Excitation 3rd Chemistry Center Day
(Coimbra, Portugal)
2021/07/14 Photochemistry of Monomeric Benzoxazole and Isocyanophenol 27th National Meeting of the Portuguese Chemical Society
(Bragança, Portugal)
2021/05/20 H-Tunneling Activated upon Vibrational Excitation 7th Portuguese Young Chemists Meeting
(Bragança, Portugal)
2021/03/30 Molecular Manipulations under Cryogenic Conditions Controlled by Infrared Vibrational Excitation (Invited Keynote Lecture/Presenting Author) 14th National Physical Chemistry Meeting
(Coimbra, Portugal)
2019/06/18 Heavy-Atom Tunneling Reaction On The Slippery Potential Energy Surface of Arynitrenes (Invited Keynote Lecture/Presenting Author) XIXth International Workshop on Quantum Atomic and Molecular Tunneling Systems
(Borovets, Bulgária)
2019/02/18 IR-Induced Chemistry: From Conformational Changes to Bond-Breaking Processes Physical Organic Chemistry: Recent Developments in Instrumentation, Structure, Theory, and Mechanisms
WE-Heraeus-Seminar (Bad Honnef, Alemanha)
2018/11/21 Selective Vibrational Excitation as a Tool for Conformational Control 24th Luso-Galego Chemistry Meeting
(Porto, Portugal)
2018/08/21 Spectroscopic Observation of Quantum Tunneling: Discoveries on the Potential Energy Surfaces of Phenylnitrenes (Invited Keynote Lecture/Presenting Author) 34th European Congress on Molecular Spectroscopy
(Coimbra, Portugal)
2018/07/04 Spontaneous and Photochemically Induced Reactions of Triplet 2-Formyl-Phenylnitrene in Low-Temperature Matrix 24th IUPAC Conference on Physical Organic Chemistry
(Faro, Portugal)
2018/01/17 Quantum Tunneling in Chemistry: 2-Formyl-Phenylnitrene - A Tale of Two "Impossible" Reactions (Invited Communication/Presenting Author) 12th National Organic Chemistry Meeting and 5th National Medicinal Chemistry Meeting
(Coimbra, Portugal)
2017/09/25 Reactivity of Triplet 2-Formyl Phenylnitrene Isolated in Noble Gas Cryogenic Matrices 2nd European Conference on Physical Chemistry
(Borgo, França)
2017/07/22 Tunneling in Triplet 2-Formyl Phenylnitrene International Symposium on Reactive Intermediates and Unusual Molecules
(Sorrento, Itália)
2017/07/16 Generation and Stabilization of Triplet 2-Formyl Phenylnitrene in Inert Cryogenic Matrices 25th National Meeting of the Portuguese Chemical Society
(Lisbon, Portugal)
2016/10/18 Bond-Shift Isomers: The Strange Case of the Co-Existence of Two Structures of a Nitrile Imine (Invited Communication/Presenting Author) 2nd Chemistry Center Day
(Coimbra, Portugal)
2016/09/24 Thermal and Photochemical Transformations of 1-Heteroaryl-1H-Tetrazoles 3rd Iberoamerican Symposium on Organic Chemistry
(Porto, Portugal)
2016/07/07 Photochemistry of Matrix-Isolated Isoxazoles 3rd Chemistry and Physics at Low Temperatures
(Biarritz, França)
2016/06/23 Photochemistry of Monomeric Isoxazoles 12th National Physical Chemistry Meeting
(Évora, Portugal)
2016/06/22 Discovering Bond-Shift Isomers in a Nitrile Imine (Presenting Author) 12th National Physical Chemistry Meeting
(Évora, Portugal)
2014/09/16 Reactivity Studies of Isoxazoles Using Matrix Isolation: A Potential New Gateway to Nitrenes (Invited Communication/Presenting Author) 1st Chemistry Center Day, Coimbra
(Coimbra, Portugal)
2014/08/26 Generation and Reactions of Nitrile Ylides and Nitrile Imines Induced by Tunable UV-Light (Presenting Author) 2nd Chemistry and Physics at Low Temperatures
(Suzdal, Rússia)
2014/04/03 The Pyrolysis of Isoxazoles Revisited: The Pivotal Role of Vinylnitrenes International Symposium on Reactive Intermediates and Unusual Molecules
(Hiroshima, Japão)
2013/05/10 Generation and Decay of a New High-Energy Conformer of Alanine (Invited Communication/Presenting Author) 11th National Physical Chemistry Meeting
(Porto, Portugal)

Orientação

Título / Tema
Papel desempenhado
Curso (Tipo)
Instituição / Organização
2023 - Atual Generation and Characterization of Carbenes from Triazole Liquid Ionic Salts: Key Studies for N-Heterocyclic Carbene Organocatalysis
Orientador de Tatiana I. C. Caneca
Master Thesis (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2021/09 - Atual Exploring Chemistry Induced by Infrared Vibrational Excitation
Orientador de Gonçalo F. Loureiro
Master Thesis (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2020/12 - Atual Quantum Mechanical Tunneling: Expanding Frontiers on Chemical Reactivity and Molecular Design
Coorientador de José P. L. Roque
PhD Thesis (Doutoramento)
Department of Chemistry, University of Coimbra, Portugal
2022/09 - 2023/09 Synthesis, Conformational and Vibrational Characterization, and Photochemical Study of Azido-Naphtols Isolated in Cryogenic Matrices (in Portuguese)
Orientador de Maria B. A. Carvalho
Master Thesis (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2023/02 - 2023/07 Exploring Gateways to Generated and Characterized Simple Triazole Carbenes in Cryogenic Matrices: Key Studies for N-Heterocyclic Carbene Organocatalysis (in Portuguese)
Orientador de Tatiana I. C. Caneca
Bsc Thesis (Licenciatura/Bacharelato)
Department of Chemistry, University of Coimbra, Portugal
2022/02 - 2022/07 Photoswiching of Spiropyrans with UV-Vis and Near-IR Light
Orientador de Mariana S. F. Peixoto
MSc Researcher (Outra)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2022/02 - 2022/07 Activate Bergman Cyclization with Near-IR Light
Orientador de Bruna D. P. Costa
MSc Researcher (Outra)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2020/09 - 2022/02 Study of Nitrilimines in Cryogenic Matrices: Generation, Characterization and Reactivity by Electronic and Vibrational Excitation (in Portuguese)
Orientador de Gil A. Ferreira
Master Thesis (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2019/05 - 2021/12 Chemistry Triggered by Infrared Vibrational Excitation: Developing a Powerful Tool for Highly-Selective Molecular Structure Manipulation
Orientador de Nelson A. M. Pereira
PostDoc Junior Researcher (Outra)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019/12 - 2020/09 Conformational Control of Proton Tunneling
Orientador de José P. L. Roque
MSc Researcher (Outra)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019/09 - 2019/11 Computational Design of Molecular Switches for Vibrational Excitation Control
Orientador de Iori Miura
IAESTE Internship (Outra)
Department of Chemistry, University of Coimbra, Portugal
2018 - 2019 Conformational Isomerization Induced by Vibrational Excitation of Second OH Stretching Overtone in Glycolamide (in Portuguese)
Orientador de Gil Almeida Ferreira
Bsc Thesis (Licenciatura/Bacharelato)
Department of Chemistry, University of Coimbra, Portugal
2017/10 - 2017/12 Chemistry Triggered by Infrared Vibrational Excitation
Coorientador de Anna Dittmar
IAESTE Internship (Outra)
Department of Chemistry, University of Coimbra, Portugal
2016/12 - 2017/08 Design of Kinetically Stable Nitrenes From Fused Benzisoxazoles and Tetrazoles
Orientador de Sandra M. V. Pinto
MSc Researcher (Outra)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2014 - 2016 Photochemistry of 1,2-Benzisoxazoles in Cryogenic Matrices. Characterization of Reactive Intermediates (in Portuguese)
Coorientador de Sandra M. V. Pinto
MSc Thesis (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2014 - 2015 The Quest for Carbenic Nitrile Imines (in Portuguese)
Coorientador de Joel Pedrosa Ferreira
BSc Thesis (Licenciatura/Bacharelato)
Department of Chemistry, University of Coimbra, Portugal
2013 - 2014 Photochemistry of Isoxazoles as a Possible Gateway to Vinylnitrenes (in Portuguese)
Coorientador de Sandra M. V. Pinto
Bsc Thesis (Licenciatura/Bacharelato)
Department of Chemistry, University of Coimbra, Portugal
2012 - 2013 Matrix Isolation Studies on Ferrocenes (in Portuguese)
Coorientador de Patrícia A. Silva
MSc Internship (Mestrado)
Department of Chemistry, University of Coimbra, Portugal

Organização de evento

Nome do evento
Tipo de evento (Tipo de participação)
Instituição / Organização
2022/11/04 - 2022/11/17 What research is carried out at UC? | LIP and CCQ (2022/11/04 - 2022/11/17)
Exposição (Coorganizador)
Department of Chemistry, University of Coimbra, Portugal
2021/12/15 - 2021/12/15 3rd Chemistry Center Day (Chair) (2021/12/15 - 2021/12/15)
Encontro (Membro da Comissão Organizadora)
Coimbra Chemistry Centre, University of Coimbra, Portugal
2013 - 2019 High School Students Visit the Lab Initiatives (2013 - 2019)
Outro (Coorganizador)
Department of Chemistry, University of Coimbra, Portugal
2018/08/19 - 2018/08/24 34th European Congress on Molecular Spectroscopy (2018/08/19 - 2018/08/24)
Congresso (Membro da Comissão Organizadora)
Department of Chemistry, University of Coimbra, Portugal
2017/07/03 - 2017/07/07 Training School on Laser Applications for Biology and Biomolecular Systems (2017/07/03 - 2017/07/07)
Oficina (workshop) (Coorganizador)
Coimbra Laser Lab, Department of Chemistry, University of Coimbra, Portugal
2017 - 2017 Summer School Activities at University of Coimbra (2017 - 2017)
Outro (Coorganizador)
Department of Chemistry, University of Coimbra, Portugal
2017 - 2017 1st FCTUC Science Show/Exposition (2017 - 2017)
Exposição (Coorganizador)
Alma Shopping, Coimbra, Portugal
2007/06/21 - 2007/06/22 8th National Physical Chemistry Meeting (2007/06/21 - 2007/06/22)
Conferência (Membro da Comissão Organizadora)
Department of Chemistry, University of Coimbra, Portugal
2006 - 2006 2nd Workshop, Chemistry an Interactive Science (2006 - 2006)
Oficina (workshop) (Coorganizador)
Department of Chemistry, University of Coimbra, Portugal
2005 - 2005 1st Workshop, Chemistry an Interactive Science (2005 - 2005)
Oficina (workshop) (Coorganizador)
Department of Chemistry, University of Coimbra, Portugal

Júri de grau académico

Tema
Tipo de participação
Nome do candidato (Tipo de grau)
Instituição / Organização
2023/09 Synthesis, Conformational and Vibrational Characterization, and Photochemical Study of Azido-Naphtols Isolated in Cryogenic Matrices (in Portuguese)
Orientador
Maria B. A. Carvalho (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2023/07 Exploring Gateways to Generated and Characterized Simple Triazole Carbenes in Cryogenic Matrices: Key Studies for N Heterocyclic Carbene Organocatalysis (in Portuguese)
Orientador
Tatiana I. C. Caneca (Outro)
Department of Chemistry, University of Coimbra, Portugal
2023/07 The Importance of Chemical Kinetics and Spectroscopy in Photochromic Dyes (in Portuguese)
Arguente principal
Edna Martins (Outro)
Department of Chemistry, University of Coimbra, Portugal
2023/07 Synthesis of Novel Indoles and Bis(indolyl)methanes: Approaches to Structures with Biological Activity
Arguente
Carla S. P. Grosso (Doutoramento)
Department of Chemistry, University of Coimbra, Portugal
2022/02/28 Study of Nitrilimines in Cryogenic Matrices: Generation, Characterization and Reactivity by Electronic and Vibrational Excitation (in Portuguese)
Orientador
Gil A. Ferreira (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2020/07 Identification of Spectral Biomarkers in Breast Cancer Cell Lines by FTIR Microspectroscopy (in Portuguese)
Arguente
Cindy Lourenço (Outro)
Department of Chemistry, University of Coimbra, Portugal
2019/07 Conformational Isomerization Induced by Vibrational Excitation of Second OH Stretching Overtone in Glycolamide (in Portuguese)
Orientador
Gil A. Ferreira (Outro)
Department of Chemistry, University of Coimbra, Portugal
2017/07 Structure and Reactivity of Pyrrole Carboxylic Acids Isolated in Cryogenic Matrices (in Portuguese)
Arguente
José P. L. Roque (Outro)
Department of Chemistry, University of Coimbra, Portugal
2016/09/22 Photochemistry of 1,2-Benzisoxazoles in Cryogenic Matrices. Characterization of Reactive Intermediates (in Portuguese)
Orientador
Sandra M. V. Pinto (Mestrado)
Department of Chemistry, University of Coimbra, Portugal
2015/07 Raman Spectroscopic Study of Cyclodextrins (in Portuguese)
Arguente
Sara Rodrigues Costa (Outro)
Department of Chemistry, University of Coimbra, Portugal

Arbitragem científica em conferência

Nome da conferência Local da conferência
2022/11/15 - 2022/11/17 VIII Edition of the NEQ/AAC Scientific Meeting Department of Chemistry, University of Coimbra
2021/12/15 - 2021/12/15 3rd Chemistry Center Day Coimbra Chemistry Centre, University of Coimbra

Curso / Disciplina lecionado

Disciplina Curso (Tipo) Instituição / Organização
2024/02 - Atual Técnicas de Purificação e Análise Estrutural de Fármacos (Technical Purification and Structural Analysis of Drugs) MSc in Industrial Pharmaceutical Chemistry (Mestrado) Faculty of Pharmacy, Universidade de Coimbra, Portugal
2023/09 - Atual Química Geral I (General Chemistry I - Laboratory classes) BSc in Geology (Licenciatura) Department of Chemistry, University of Coimbra, Portugal
2023/09 - Atual Química Geral (General Chemistry - Laboratory classes) BSc in Engineering Physics / BSc in Biomedical Engineering (Licenciatura) Department of Chemistry, University of Coimbra, Portugal
2023/09 - Atual Química Geral (General Chemistry) BSc in Biochemistry (Licenciatura) Department of Chemistry, University of Coimbra, Portugal
2021/09 - Atual Identificação e Análise de Compostos Orgânicos (Identification and Analysis of Organic Compounds) MSc in Chemistry / MSc in Forensic Chemistry (Mestrado) Department of Chemistry, University of Coimbra, Portugal
2020/02 - 2020/07 Química Geral II (General Chemistry II) BSc in Chemistry / BSc in Physics (Licenciatura) Department of Chemistry, University of Coimbra, Portugal
2019/09 - 2020/02 Identificação e Análise de Compostos Orgânicos (Identification and Analysis of Organic Compounds) MSc in Chemistry / MSc in Forensic Chemistry (Mestrado) Department of Chemistry, University of Coimbra, Portugal
2019/09 - 2020/02 Química Geral (General Chemistry) BSc in Biology (Licenciatura) Department of Chemistry, University of Coimbra, Portugal
2017/07/04 - 2017/07/04 IR Spectroscopy and Photochemistry in Cryogenic Media Training School on Laser Applications for Biology and Biomolecular Systems Coimbra Laser Lab, Department of Chemistry, University of Coimbra, Portugal
2005/01 - 2005/07 Química Analítica (Analytical Chemistry) BSc in Pharmaceutical Sciences (Licenciatura) Department of Chemistry, University of Coimbra, Portugal

Entrevista (jornal / revista)

Descrição da atividade Jornal / Forum
2022/11/24 Unprecedented Simultaneous Quantum Tunnelling Reaction Discovered Chemistry Word

Membro de associação

Nome da associação Tipo de participação
2013 - Atual Portuguese Chemical Society Member
2013 - Atual Coimbra Chemistry Centre (CQC), University of Coimbra, Portugal Integrated Member

Membro de comissão

Descrição da atividade
Tipo de participação
Instituição / Organização
2024/01 - Atual Executive Board of the Coimbra Chemistry Centre
Membro
Coimbra Chemistry Centre, University of Coimbra, Portugal
2019 - Atual Executive Board of the Coimbra Laser Lab
Membro
Coimbra Laser Lab, Department of Chemistry, University of Coimbra, Portugal
2021/11 - 2023/12 Executive Board of the Coimbra Chemistry Centre
Membro
Coimbra Chemistry Centre , University of Coimbra, Portugal
2019/10 - 2021/10 Executive Board of Coimbra Chemistry Centre
Membro
Coimbra Chemistry Centre , University of Coimbra, Portugal
2013 - 2015 Representation Committe in the Postdoc Platform, PostDoc@UC
Membro
Universidade de Coimbra, Portugal

Outro júri / avaliação

Descrição da atividade Instituição / Organização
2016 - Atual Member of the jury in 11 different calls to research fellowships to BSc, MSc and PhD researchers and to PostDocs and Junior researchers. Coimbra Chemistry Centre, University of Coimbra, Portugal
2023/09/26 - 2023/09/26 Member of the Jury in recognition of 1 MSc Degree (Aklima KaKon, MSc in Chemistry, National University of Gazipur, Bangaldesh) Department of Chemistry, University of Coimbra, Portugal
2022/05/24 - 2022/05/24 Member of the Jury in recognition of 1 BSc Degree (Maria Fernanda de Aguiar Izidoro, BSc in Chemistry, Universidade Federal de São Carlos, Brasil) Department of Chemistry, University of Coimbra, Portugal
2021/06/22 - 2021/06/22 Member of the Jury in 1 PhD project thesis - Quantum Mechanical Tunneling: Expanding Frontiers on Chemical Reactivity and Molecular Design - José P. L. Roque Department of Chemistry, University of Coimbra, Portugal

Revisão ad hoc de artigos em revista

Nome da revista (ISSN) Editora
2023/10 - Atual Journal of the American Chemical Society American Chemical Society
2023/08 - Atual ChemCatChem Wiley-VCH
2022/11 - Atual Nature Communications Springer Nature
2022/10 - Atual Chemical Science Royal Society of Chemistry
2021/08 - Atual Journal of Physical Organic Chemistry Wiley-VCH
2021/03 - Atual The Journal of Chemical Physics American Institute of Physics
2020/03 - Atual The Journal of Physical Chemistry American Chemical Society
2019/12 - Atual Angewandte Chemie Wiley-VCH
2019/09 - Atual European Journal of Organic Chemistry Wiley-VCH
2019/08 - Atual Australian Journal of Chemistry CSIRO Publishing
2016/10 - Atual Organic Letters American Chemical Society
2015/12 - Atual New Journal of Chemistry Royal Society of Chemistry
2015/07 - Atual Physical Chemistry Chemical Physics Royal Society of Chemistry
2014/04 - Atual The Journal of Organic Chemistry American Chemical Society
2013/07 - Atual Tetrahedron Letters Elsevier
2013/06 - Atual Journal of Molecular Structure Elsevier

Tutoria

Tópico Nome do aluno
2021/02 - 2021/07 Switching of a Methoxy Rotor by Vibrational Excitation of a NH2 Antenna (in Portuguese) Gonçalo F. Loureiro
2020/02 - 2020/07 Photochemistry of 4-Azido-3,5-Difluoroaniline: Theoretical Prediction of Controlled Reactivity by Selective Vibrational Excitation in Cryogenic Matrices (in Portuguese) Gil A. Ferreira
Distinções

Prémio

2019 Auxiliary Researcher Position
Fundação para a Ciência e a Tecnologia, Portugal
2019 Junior Researcher Position
Department of Chemistry, University of Coimbra, Portugal
2013 Postdoctoral Fellowship
Fundação para a Ciência e a Tecnologia, Portugal
2013 Postdoctoral Fellowship
Université de Fribourg, Suiça
2007 Doctoral Fellowship
Fundação para a Ciência e a Tecnologia, Portugal
2004 Caixa Geral de Depósitos Award - Best final mark, BSc Degree
Caixa Geral de Depositos, Portugal
2003 BPI Fernando Alves Award - Best mark of the year, BSc Degree
BPI, Portugal

Outra distinção

2014 Outstanding Presentation Award at the Young Investigators Section
2nd Chemistry and Physics at Low Temperatures, Rússia